Russian Journal of Inorganic Chemistry, Tập 42,Trang 951-1448Chemical Society., 1997 |
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... activation AS * can be calculated by the equations and AS * = AS cond - Rlnk AG * = AGcond + RT lnk . ( 5 ) ( 6 ) ... activation is positive ; that is , the activated complex involves solvent molecules breaking the bulk structure of the ...
... activation AS * can be calculated by the equations and AS * = AS cond - Rlnk AG * = AGcond + RT lnk . ( 5 ) ( 6 ) ... activation is positive ; that is , the activated complex involves solvent molecules breaking the bulk structure of the ...
Trang 1398
... Activation Parameters of Internal Hindered Rotation of Benzaldoximato Ligand in Fluoro Molybdenum ( VI ) and Tungsten ( VI ) Complexes as Determined by 19F DNMR S. G. Sakharov , V. D. Butskii , and Yu . A. Buslaev Kurnakov Institute of ...
... Activation Parameters of Internal Hindered Rotation of Benzaldoximato Ligand in Fluoro Molybdenum ( VI ) and Tungsten ( VI ) Complexes as Determined by 19F DNMR S. G. Sakharov , V. D. Butskii , and Yu . A. Buslaev Kurnakov Institute of ...
Trang 1404
... activation energy of isomerization : ( i ) steric ( bulky substituents in the ligand ) , ( ii ) electronic ( donating ability of the ligand and accepting ability of the central atom ) , and ( iii ) the effect of medium ( solvent ...
... activation energy of isomerization : ( i ) steric ( bulky substituents in the ligand ) , ( ii ) electronic ( donating ability of the ligand and accepting ability of the central atom ) , and ( iii ) the effect of medium ( solvent ...
Nội dung
Vol 42 No 7 | 951 |
Triple Triphosphate NaKTbP3010 | 958 |
Relative Reactivity of Oxo Anions to MetalII Hydroxides | 964 |
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Academy of Sciences acid analysis angles anion atoms bismuth bond lengths calculated cation chelate Chem chemical shifts chloride cm-¹ complexes composition compounds concentration coordination copper(II corresponding crystal structure curves decomposition decrease determined distances electron energy English Translation Copyright enthalpy equation equilibrium experimental extraction fluorine formation frequencies H₂O Hayka/Interperiodica Publishing Russia heat hydrate hydrogen bonds hydroxide increase Inorganic Chemistry isomer kcal/mol Khim kJ/mol LiClO4 ligand lithium MAHK Hayka/Interperiodica Publishing melting metal method mixture mol/l Moscow Neorg Original Russian Text oxide oxygen atoms perchlorate phase diagram Phys platinum(IV plexes podand polyhedra polyhedron proton ratio reaction Russia Received Russian Academy Russian Journal Russian Text Copyright salts samples sodium solid solutions solvent space group spectrum studied synthesis Table temperature thermal thermodynamic tion titration ture unit cell unit cell parameters values vibration water molecules X-ray diffraction X-ray powder diffraction