Russian Journal of Inorganic Chemistry, Tập 7,Phần 1British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1962 |
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Trang 158
... plexes Ag and Ag- have been detected . The former is the predominant with Nal from 0.12 to 1.15 M , the latter with NaI from 1.5 to 6 M. The calculated formation con- stants are , respectively , 1.23 × 1014 and 2.46 × 1016 ( Table 3 ) ...
... plexes Ag and Ag- have been detected . The former is the predominant with Nal from 0.12 to 1.15 M , the latter with NaI from 1.5 to 6 M. The calculated formation con- stants are , respectively , 1.23 × 1014 and 2.46 × 1016 ( Table 3 ) ...
Trang 159
... plexes MXm and MYm were determined from the equations : 22 8 exponent of the instability constant จตุ AgC Fx ( m ) = FX + ᎡᎢ 4m log Rm , 0 , Fy ( m ) = Fy + ᎡᎢ 4m log Ro , m , ( 7 ) where Rm , o and Ro , m are the formation ...
... plexes MXm and MYm were determined from the equations : 22 8 exponent of the instability constant จตุ AgC Fx ( m ) = FX + ᎡᎢ 4m log Rm , 0 , Fy ( m ) = Fy + ᎡᎢ 4m log Ro , m , ( 7 ) where Rm , o and Ro , m are the formation ...
Trang 234
... plexes of most elements , the very existence of cobalt ( III ) complexes containing ligands such as nitro , bromo , etc. would be impossible . If the equilibrium were mobile , the tervalent cobalt would rapidly oxidise the nitrite to ...
... plexes of most elements , the very existence of cobalt ( III ) complexes containing ligands such as nitro , bromo , etc. would be impossible . If the equilibrium were mobile , the tervalent cobalt would rapidly oxidise the nitrite to ...
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JOURNAL | 1 |
Complexes of platinum with tetramethylthiuram disulphide bisdimethylthio | 9 |
Infrared absorption spectra of bi and quadrivalent platinum aminoacido | 15 |
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Akad alanine alcohol alkali alloys ammonia ammonium analysis anions aqueous solution binary bond cadmium calculated cations Chem chemical chemistry chloride cobalt(III coefficient complex formation composition compounds concentration constant corresponding crystallisation crystals decomposition dehydration determined diethanolamine disodium pyrophosphate dissociation endothermic endothermic effect equilibrium diagram ethanol ether eutectic eutectic point EXPERIMENTAL extraction formed H₂O hafnium heating curves hydrates hydrogen increase Inorg ions isotherms K₂ kcal Khim Kurnakov ligand liquid lithium melting metal method mixture molar mole molecules mono Na₂SO NaCl NaOH Nauk SSSR Neorg niobium nitrate nitric nitrile Obshch obtained oxide P₂O perchlorate phosphate platinum plexes potassium precipitate prepared PtCl pyridine pyrophosphate ratio reaction reagent reciprocal system Russ salt shows sodium sodium triphosphate solid solutions solu solubility specimen stable studied sulphate Table temperature thermal thermogram thiuram tion titanium values vanadium vanadium(II X-ray Zhur zirconium