Russian Journal of Inorganic Chemistry, Tập 4,Trang 659-1328Chemical Society., 1959 |
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Kết quả 1-3 trong 52
Trang 689
... ligands , possessing reducing properties , is due to some form of interaction between the 5d valency electrons of the platinum and the electrons of the ligands . In the earlier explanation of the trans effect based on polarisation ...
... ligands , possessing reducing properties , is due to some form of interaction between the 5d valency electrons of the platinum and the electrons of the ligands . In the earlier explanation of the trans effect based on polarisation ...
Trang 774
... ligands are : F = 3.95 ; O 3.5 ; C1 = 3.0 ; Br = 2.8 ; I , S , C = 2.5 . Thus the trans effect increases as the dif- ference between the electronegativities of atoms decreases , so that the trans effect is strongest in Pt compounds ...
... ligands are : F = 3.95 ; O 3.5 ; C1 = 3.0 ; Br = 2.8 ; I , S , C = 2.5 . Thus the trans effect increases as the dif- ference between the electronegativities of atoms decreases , so that the trans effect is strongest in Pt compounds ...
Trang 775
... ligands will both be zero . Hence the ability of atoms to exert a trans effect depends directly on the degree of co- valency of the bonds with a particular atom . The trans effect is shown by the labilisation of a ligand in the trans ...
... ligands will both be zero . Hence the ability of atoms to exert a trans effect depends directly on the degree of co- valency of the bonds with a particular atom . The trans effect is shown by the labilisation of a ligand in the trans ...
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2H₂O absorption acetone acid Akad AlBr alcohol alkali alloys aluminium Amer ammonium analysis anion annealed anorg aqueous solutions atoms beryllium calculated carbonate cation cerium Chem Chemistry chloride coefficient complex compounds composition concentration conductance containing coprecipitation corresponding crystallisation crystals curve decomposition determined diagram dioxan electrons equation equilibrium ethanol ether eutectic experimental formation formed glaserite H₂O heating HNO3 hydration hydrogen hydroxide increase indium instability constants ionic ions isotherms Khim lattice ligands liquid melting metal method mixture molal molar mole molecules Moscow Na₂SO NaCl NaOH Nauk SSSR Neorg Obshch obtained oxalate oxide platinum potassium precipitate prepared pyridine ratio reaction ruthenium salt saturated sections shows sodium solid phase solid solutions solu solubility solvent stability structure studied sulphate Table temperature thermal Thermogram thorium tion trans effect uranyl nitrate values vapour pressure X-ray yield Zhur