Russian Journal of Inorganic Chemistry, Tập 11,Phần 1British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1966 |
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Trang 61
... ligands and ( or ) central ions . The direction of the changes in the strength of individual bonds is determined chiefly by the ratio of the electrostatic potentials ( z / r ) ; the strength of the bond for- med by the particle with ...
... ligands and ( or ) central ions . The direction of the changes in the strength of individual bonds is determined chiefly by the ratio of the electrostatic potentials ( z / r ) ; the strength of the bond for- med by the particle with ...
Trang 62
... ligands X and Y in compounds containing only one type of ligand have identical valency- -state energies : $ x ° = @ y ° = ¶A ° . Under these conditions the coefficient a is independent of the nature of the ligands , and in accordance ...
... ligands X and Y in compounds containing only one type of ligand have identical valency- -state energies : $ x ° = @ y ° = ¶A ° . Under these conditions the coefficient a is independent of the nature of the ligands , and in accordance ...
Trang 63
... ligands in the formation of mixed compounds as a result of the interaction of coordi- nated particles of different type . If on formation of these compounds the energies of the valency states of the metal ion and ligands decrease , the ...
... ligands in the formation of mixed compounds as a result of the interaction of coordi- nated particles of different type . If on formation of these compounds the energies of the valency states of the metal ion and ligands decrease , the ...
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acid solutions Akad alcohol alkali aluminium aluminium chloride amine analysis anion aqueous solutions bond boron trichloride boron trifluoride caesium calculated cation Chem chemical Chemistry chloride chromium(II cm-¹ Co(DH cobalt complex composition concentration coordination corresponding crystals curve decomposition decrease dehydration determined diagram diborane diglyme electrode enthalpies of dissolution equilibrium ether addition compound ethylenediamine europium eutectic extracting agent formed g-ion gadolinium germanium dioxide H₂O hafnium heated hydrates hydrochloric acid hydrogen hydroxide increase Inorg ions iron(III isothermal kcal Khim ligands melting metal method mixture mmoles molar mole molecules Moscow MZPC Nauk SSSR Neorg nickel niobium obtained optical density orthosilicate oxide potassium precipitate prepared PtCl pyrophosphate quantity ratio reaction reduction residue rubidium Russ salt shows sodium tetrahydroaluminate solubility solvents studied sulphate Table temperature ternary tetrahydrofuran thermal thiourea tion titration triammine uranium(IV values X-ray Zhur zirconium