Russian Journal of Inorganic Chemistry, Tập 11,Phần 1British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1966 |
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Trang 23
... ethylenediamine ( Ref . 6 , p.40 ; ref.11 ) . This suggested that the amido- -inversion is due to spatial changes resulting from a change in the nature of the bonding between the platinum and the coordinated ammonia or amine on ...
... ethylenediamine ( Ref . 6 , p.40 ; ref.11 ) . This suggested that the amido- -inversion is due to spatial changes resulting from a change in the nature of the bonding between the platinum and the coordinated ammonia or amine on ...
Trang 72
... ( ethylenediamine ) chromium ( III ) ion in accord- ance with Eqn . ( 1 ) , to start a new cycle . In addition to this direction , the aquation also takes place with the replacement of ethylenediamine molecules by water molecules . Free ...
... ( ethylenediamine ) chromium ( III ) ion in accord- ance with Eqn . ( 1 ) , to start a new cycle . In addition to this direction , the aquation also takes place with the replacement of ethylenediamine molecules by water molecules . Free ...
Trang 510
... ethylenediamine molecule from the inner sphere of the complex cation . If such a process of preliminary detach- ment of ethylenediamine were to be observed , the deamina- tion of the liberated ethylenediamine ligand would be expected ...
... ethylenediamine molecule from the inner sphere of the complex cation . If such a process of preliminary detach- ment of ethylenediamine were to be observed , the deamina- tion of the liberated ethylenediamine ligand would be expected ...
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acid solutions Akad alcohol alkali aluminium aluminium chloride amine analysis anion aqueous solutions bond boron trichloride boron trifluoride caesium calculated cation Chem chemical Chemistry chloride chromium(II cm-¹ Co(DH cobalt complex composition concentration coordination corresponding crystals curve decomposition decrease dehydration determined diagram diborane diglyme electrode enthalpies of dissolution equilibrium ether addition compound ethylenediamine europium eutectic extracting agent formed g-ion gadolinium germanium dioxide H₂O hafnium heated hydrates hydrochloric acid hydrogen hydroxide increase Inorg ions iron(III isothermal kcal Khim ligands melting metal method mixture mmoles molar mole molecules Moscow MZPC Nauk SSSR Neorg nickel niobium obtained optical density orthosilicate oxide potassium precipitate prepared PtCl pyrophosphate quantity ratio reaction reduction residue rubidium Russ salt shows sodium tetrahydroaluminate solubility solvents studied sulphate Table temperature ternary tetrahydrofuran thermal thiourea tion titration triammine uranium(IV values X-ray Zhur zirconium