Russian Journal of Inorganic Chemistry, Tập 11,Phần 1British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1966 |
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Trang 44
... electrode . Reaction ( 4 ) is completely reversible only in sufficiently acidic solutions . In weakly acidic solutions , hydrolysis occurs and the course of the electrode processes is altered radically . The polarograms obtained with ...
... electrode . Reaction ( 4 ) is completely reversible only in sufficiently acidic solutions . In weakly acidic solutions , hydrolysis occurs and the course of the electrode processes is altered radically . The polarograms obtained with ...
Trang 45
... electrode , V -1.6 Polarogram for a solution containing 1.1 × 10-3 M UO2Cl2 , 0.1 M KCl , and 0.01 M HCl . Fig . 7 . current strength , μA 2.50 200 150 100 0 50 0 -06 -10 potential , V -14 -1.8 Polarogram for a solution containing 2.9 ...
... electrode , V -1.6 Polarogram for a solution containing 1.1 × 10-3 M UO2Cl2 , 0.1 M KCl , and 0.01 M HCl . Fig . 7 . current strength , μA 2.50 200 150 100 0 50 0 -06 -10 potential , V -14 -1.8 Polarogram for a solution containing 2.9 ...
Trang 149
... electrode could not be used because of its catalytic influence on the oxidation of H , PO , by Fe " ions , a graphite electrode prepared from spectroscopically pure carbon ( working surface area 2 cm2 ) was used as indicator electrode ...
... electrode could not be used because of its catalytic influence on the oxidation of H , PO , by Fe " ions , a graphite electrode prepared from spectroscopically pure carbon ( working surface area 2 cm2 ) was used as indicator electrode ...
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acid solutions Akad alcohol alkali aluminium aluminium chloride amine analysis anion aqueous solutions bond boron trichloride boron trifluoride caesium calculated cation Chem chemical Chemistry chloride chromium(II cm-¹ Co(DH cobalt complex composition concentration coordination corresponding crystals curve decomposition decrease dehydration determined diagram diborane diglyme electrode enthalpies of dissolution equilibrium ether addition compound ethylenediamine europium eutectic extracting agent formed g-ion gadolinium germanium dioxide H₂O hafnium heated hydrates hydrochloric acid hydrogen hydroxide increase Inorg ions iron(III isothermal kcal Khim ligands melting metal method mixture mmoles molar mole molecules Moscow MZPC Nauk SSSR Neorg nickel niobium obtained optical density orthosilicate oxide potassium precipitate prepared PtCl pyrophosphate quantity ratio reaction reduction residue rubidium Russ salt shows sodium tetrahydroaluminate solubility solvents studied sulphate Table temperature ternary tetrahydrofuran thermal thiourea tion titration triammine uranium(IV values X-ray Zhur zirconium