Russian Journal of Inorganic Chemistry, Tập 47,Số phát hành 9-12Chemical Society., 2002 |
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Trang 1541
... HCIO4 nH2O and DCIO4 · nD2O , where n = 1-2 . The signatures of solvation of the CIO ion by proton hydrates and simultaneously by HCIO4 ( DC104 ) molecules are discovered . The parameters of a hydrogen bond formed by CIO , and HCIO4 are ...
... HCIO4 nH2O and DCIO4 · nD2O , where n = 1-2 . The signatures of solvation of the CIO ion by proton hydrates and simultaneously by HCIO4 ( DC104 ) molecules are discovered . The parameters of a hydrogen bond formed by CIO , and HCIO4 are ...
Trang 1547
... HCIO4 . The cat- ions have no narrow maxima in either the IR or the Raman spectra of the melt , which makes their detection difficult and quantifying almost impossible . The v ( OH ) band in H3O + · xH2O are unresolved , but a shoulder ...
... HCIO4 . The cat- ions have no narrow maxima in either the IR or the Raman spectra of the melt , which makes their detection difficult and quantifying almost impossible . The v ( OH ) band in H3O + · xH2O are unresolved , but a shoulder ...
Trang 1548
... HCIO4 . Note also that the & ( HOCl ) frequency , equal to 1330 cm - 1 , is too low for such a hypothetical H - bonded complex . A water mole- cule would have to yield a more strongly bonded com- plex with HCIO4 than with CIO4 . However ...
... HCIO4 . Note also that the & ( HOCl ) frequency , equal to 1330 cm - 1 , is too low for such a hypothetical H - bonded complex . A water mole- cule would have to yield a more strongly bonded com- plex with HCIO4 than with CIO4 . However ...
Nội dung
Vol 47 No 10 2002 | 1456 |
Vol 47 No 11 2002 | 1603 |
Hydrothermal Synthesis of Nanocrystalline Powders | 1609 |
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ų absorption acid analysis angles anion aqueous solution atoms band bond lengths calculated cations chelate Chem chemical cm-¹ complex composition compounds concentration coordination sphere corresponding crystal structure crystallographic curve decrease determined diffraction patterns dimers distances electron English Translation Copyright experimental formation formed g/cm³ H-bonds H₂O HCIO4 hydrogen bonds interaction ionic ions Khim ligands lithium MAIK Nauka/Interperiodica melting metal method mixture Mo atoms mol/l Moscow Nauk Neorg nitrate octahedra Original Russian Text oxide oxygen atoms perchlorate phase diagram phthalocyanine physicochemical pivalate pivalic acid plexes polyhedron proton Raman ratio reaction refined region Russia Received Russian Academy Russian Text Copyright salt samples sodium solid solutions solubility space group spectra spectrum studied synthesis Table temperature ternary thermal tion ture unit cell parameters values VD polyhedra vibrations water molecules X-ray diffraction X-ray powder diffraction