Russian Journal of Inorganic Chemistry, Tập 16,Phần 1British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1971 |
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Trang 313
... ligands in the inner sphere is determined by the nature of the central atom and the type of the chemical metal- ligand bond . Ligands with an expressed covalent bond of donor - acceptor type are compatible with difficulty with other ligands ...
... ligands in the inner sphere is determined by the nature of the central atom and the type of the chemical metal- ligand bond . Ligands with an expressed covalent bond of donor - acceptor type are compatible with difficulty with other ligands ...
Trang 314
... ligands . Finally , a measure of the compatibility of ligand Y with ligand X can be given by the equilibrium constant of the reaction ( the addition constant ) MX + Y MXY [ MXY ] Ky = [ MX ] [ Y ] ( 5 ) ( 5a ) It can readily be shown ...
... ligands . Finally , a measure of the compatibility of ligand Y with ligand X can be given by the equilibrium constant of the reaction ( the addition constant ) MX + Y MXY [ MXY ] Ky = [ MX ] [ Y ] ( 5 ) ( 5a ) It can readily be shown ...
Trang 565
... ligand . These results suggest that initially the phosphorus - containing ligand is introduced axially and then a second such ligand enters in the equatorial plane . Probably its bonding with Crl is due to the phosphorus developing only ...
... ligand . These results suggest that initially the phosphorus - containing ligand is introduced axially and then a second such ligand enters in the equatorial plane . Probably its bonding with Crl is due to the phosphorus developing only ...
Nội dung
INORGANIC | 1 |
Reaction of certain arsenides of Group IIV elements | 8 |
Thermal decomposition of molybdenum pentachloride | 15 |
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absorption bands absorption spectra Akad alcohol alkali aluminium ammonium analysis anhydrous aqueous solutions atom caesium calculated carbonate cerium Chem chemical chloride cm-¹ cm¹ cobalt(III composition compounds concentration coordination copper corresponding crystallisation crystals curves density determined dimethylformamide dioxan dissociation endothermic effect equilibrium diagram erbium eutectic experimental extraction formed groups H₂O heating hydrogen hydroxide infrared spectra Inorg investigated ions iron(III isothermal kcal Khim lanthanide lanthanum lattice ligand lithium metal methanol method mixture molar mole molecules molybdenum Moscow Nauk SSSR Neorg obtained oxide parameters perxenate platinum(II plexes potassium potentiometric praseodymium precipitate prepared present pyridine range ratio reaction Russ salt scandium shows sodium perxenate solid phase solid solutions solubility solvent specimens spectrum stability constants strengite sulphide synthesis Table temperature thermal decomposition thiocyanate tion titration Translated into Russian vanadium vanadium(V vibrations X-ray diffraction Zhur zirconium