Russian Journal of Inorganic Chemistry, Tập 48,Số phát hành 5-8British Library Lending Division with the cooperation of the Royal Society of Chemistry, 2003 |
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Trang 861
... electron - density maps demonstrates that the multipole model reflects the characteristic features of the chemical constitution and the distribution of the 3d electrons of the atom much better than the spherical model . The populations ...
... electron - density maps demonstrates that the multipole model reflects the characteristic features of the chemical constitution and the distribution of the 3d electrons of the atom much better than the spherical model . The populations ...
Trang 863
... electron - density map passing through two adjacent Cr octahedra and the common O atom ( like in pyrite ) . The map has a double electron - density peak with a height of 0.4 e / Å3 between the Cr atoms in the vicinity of the shared face ...
... electron - density map passing through two adjacent Cr octahedra and the common O atom ( like in pyrite ) . The map has a double electron - density peak with a height of 0.4 e / Å3 between the Cr atoms in the vicinity of the shared face ...
Trang 867
... electron transfer from the oxygen atom to Cr3 + led to a decrease in the charge on the chromium ion to + 2.325e . It was noted that the most striking feature of the electron - density distribution was polarization of the 3d3 electrons ...
... electron transfer from the oxygen atom to Cr3 + led to a decrease in the charge on the chromium ion to + 2.325e . It was noted that the most striking feature of the electron - density distribution was polarization of the 3d3 electrons ...
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Vol 48 No 5 | 622 |
Synthesis and Crystal Structure | 632 |
Synthesis and Study | 642 |
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ų absorption acetonitrile acid analysis angles anion aqueous atoms band bond lengths calcd calculated carbon cations Chem chemical chloride cluster cm-¹ complexes composition concentration corresponding crystal structure Crystallogr curves decomposition decrease electron English Translation Copyright europium experimental extraction formation formed fullerenes H NMR H₂O hydrates hydrogen increases Inorganic Chemistry interaction ionic ions IR spectroscopy iron(III isomers Khim kJ/mol ligand luminescence MAIK Nauka/Interperiodica metal mixture mmol mol/l molecular molecules Moscow Nauk Neorg NMR spectra octahedra Original Russian Text oxide oxohydroxide parameters phase Phys plexes polyhedron protons quinaldinates range ratio reaction refined region Russia Received Russian Academy Russian Journal Russian Text Copyright ruthenium samples scandium signals sodium solid solutions solubility solvent space group spectroscopy spectrum stability studied sulfate synthesis Table thermal tion unit cell values VD polyhedra vibrations X-ray crystallography X-ray diffraction xerogels