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The packing type is determined by the MFM angle around the bridging fluorine atom . In ( MF5 ) 4 tetramers , a close packing of the F atoms is cubic at MFM 180 ° and hexagonal at the MFM value sufficiently different from 180 ° .
The packing type is determined by the MFM angle around the bridging fluorine atom . In ( MF5 ) 4 tetramers , a close packing of the F atoms is cubic at MFM 180 ° and hexagonal at the MFM value sufficiently different from 180 ° .
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NQR frequencies v of axial ( dashed line ) and equatorial ( solid line ) chlorine atoms in ( MC15 ) 2 as a function of bridging halogen frequencies . Empty circles are axial and filled circles are equatorial atoms .
NQR frequencies v of axial ( dashed line ) and equatorial ( solid line ) chlorine atoms in ( MC15 ) 2 as a function of bridging halogen frequencies . Empty circles are axial and filled circles are equatorial atoms .
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A sharp increase in the bridging halogen frequencies as compared to the terminal frequencies is caused by a pr - electron density increase due to a weaker p1 - dr bonding between the bridging atoms and the metal .
A sharp increase in the bridging halogen frequencies as compared to the terminal frequencies is caused by a pr - electron density increase due to a weaker p1 - dr bonding between the bridging atoms and the metal .
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Vol 41 No 1 | 1 |
Synthesis and Characterization | 7 |
Deviation from Stoichiometry in Mercury Chalcochromite HgCr₂Se4 | 23 |
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absorption according acid addition analysis angles anions aqueous atoms band bismuth bond bridging calculated carbon cations changes Chem chemical Chemistry chloride cm-¹ complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease dependence determined distances effect electron elements energy equation equilibrium experimental extraction formation frequency function H₂O heating higher hydrogen increase indicates Inorganic interaction ions Journal Khim ligands measured melting metal method mixture mol/l molecules Moscow Neorg observed obtained occur organic oxidation oxygen atoms parameters peak peritectic phase Physics points position possible prepared present properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples Sciences shows similar sodium solid solutions space group spectra spectrum stability structure studied synthesis Table temperature thermal tion Translation unit values vibrations X-ray diffraction
Thông tin thư mục
| Tiêu đề | Russian Journal of Inorganic Chemistry, Tập 41,Số phát hành 1-4 |
| Cộng tác viên | British Library. Lending Division, Chemical Society (Great Britain), Royal Society of Chemistry (Great Britain) |
| Nhà xuất bản | British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1996 |
| Xuất lời trích dẫn | BiBTeX EndNote RefMan |