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Trang S-60
The V - N bonds trans to the peroxo ligand are unexpectedly longer ( especially in IX ) than the V - N bonds trans to ... [ 15 ] arrived at the con- clusion that structures IX and X contain both peroxo and superoxo ligands , which are ...
The V - N bonds trans to the peroxo ligand are unexpectedly longer ( especially in IX ) than the V - N bonds trans to ... [ 15 ] arrived at the con- clusion that structures IX and X contain both peroxo and superoxo ligands , which are ...
Trang S-66
eq eq equatorial bond , the Bipy ligand can rotate around the stronger V - Neg bond so that the second N atom trans- fers to the equatorial plane , approximately in the trans position to the extant peroxo group .
eq eq equatorial bond , the Bipy ligand can rotate around the stronger V - Neg bond so that the second N atom trans- fers to the equatorial plane , approximately in the trans position to the extant peroxo group .
Trang S-78
Given the complete transfer of two electrons and their redistribution in the MOS of л - acceptor ligands ( or ... In terms of this concept , both the shortening of O - 0 bonds and SMTI of the peroxo ligand can be explained . π ...
Given the complete transfer of two electrons and their redistribution in the MOS of л - acceptor ligands ( or ... In terms of this concept , both the shortening of O - 0 bonds and SMTI of the peroxo ligand can be explained . π ...
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Vol 48 No 9 | 1282 |
Simultaneous English language translation of the journal is available from MAIK NaukaInterperiodica Russia | 1446 |
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absorption acid activation analysis angles anion atoms band bond calculated cations Chem chemical Chemistry cm-¹ complexes components composition compounds concentration constant containing coordination Copyright corresponding crystal crystal structure curves decreases determined diagram distances effect electron energy experimental field formation formed function heating hydrogen increases Inorganic intensity interaction ions Journal Khim layer ligand materials measured melting metal method mixture molecules Moscow Neorg Note observed obtained oxidation oxygen parameters phase Physics positions prepared properties range ratio reaction REFERENCES refined reflections region respectively ring Russian salt samples Sciences shifts shown shows signals single sodium solid solid solutions solubility solutions space space group spectra spectrum spinel stability structure studied Synthesis Table temperature thermal tion trans transition Translation values vibrations X-ray diffraction