Russian Journal of Inorganic Chemistry, Tập 40,Trang 1527-2028Chemical Society., 1995 |
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Trang 1607
... perchlorate as the concentration of ammonia increases from 0 to 14 mol / l was attributed to the formation of the outer - sphere ammoniates of composition M ( NH3 ) 3 , where n = 1 - 4 and M3 + are hexaamminerhodium ( III ) and ...
... perchlorate as the concentration of ammonia increases from 0 to 14 mol / l was attributed to the formation of the outer - sphere ammoniates of composition M ( NH3 ) 3 , where n = 1 - 4 and M3 + are hexaamminerhodium ( III ) and ...
Trang 1672
... perchlorate systems . In the temperature range 90 - 180 ° C , the eutectic mixture , containing 35.5 mol % [ ( NH2 ) 3C ] CIO4 and 64.5 mol % [ ( C4H9 ) 4N ] CIO4 , is a stable , colorless mobile liquid . Compositions of solvent - melts ...
... perchlorate systems . In the temperature range 90 - 180 ° C , the eutectic mixture , containing 35.5 mol % [ ( NH2 ) 3C ] CIO4 and 64.5 mol % [ ( C4H9 ) 4N ] CIO4 , is a stable , colorless mobile liquid . Compositions of solvent - melts ...
Trang 1719
... perchlorate ( v , cm - 1 ) : 710 s , 870 s , 1000 s , 1040 s , 1240 s , and 1280 vs. The IR spectrum of ethyl perchlorate , pre- pared by the reaction of ethanol and Cl2O , in CCl4 , con- tains the same set of absorption bands [ 20 ] ...
... perchlorate ( v , cm - 1 ) : 710 s , 870 s , 1000 s , 1040 s , 1240 s , and 1280 vs. The IR spectrum of ethyl perchlorate , pre- pared by the reaction of ethanol and Cl2O , in CCl4 , con- tains the same set of absorption bands [ 20 ] ...
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13C NMR acetonitrile acid Akad analysis angles anion aqueous solutions basis set bismuth bond lengths calcd calcium calculations cation Chem chemical chemical shifts chloride cm-¹ complexes composition compounds concentration constants coordination corresponding crown ether crystals curves determined electron electron correlation energy English Translation Copyright enthalpy equilibrium ethanol ethylenediamine experimental extraction fluoride formation frequencies H₂O Hayka/Interperiodica Publishing Russia heating hydrogen bonds Inorg Inorganic Chemistry interaction ionic ions isomer kcal/mol Khim kJ/mol ligand magnesium melt metal mol/l molecule monoclinic Moscow Nauk SSSR Neorg nitrate NMR spectra NMR Spectroscopy obtained Original Russian Text oxides oxygen atoms perchlorate peritectic platinum(II plexes precipitate Raman range ratio reaction Russia Received Russian Academy Russian Text Copyright salts samples sodium solid phase solu solubility solvent spectrum stability structure studied sulfate synthesis Table temperature ternary thermal thermodynamic tion ture unit cell values vibrations X-ray diffraction