Russian Journal of Inorganic Chemistry, Tập 43,Số phát hành 9-12British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1998 |
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Trang 1405
... bridging bonds are dominated by interaction of the 3p AO of aluminum with the 2p , AO of bridging fluorine atoms . In this case , 2p . ( F ) -3p , ( Al ) interaction in the bridging bond becomes weaker compared to that in the isolated ...
... bridging bonds are dominated by interaction of the 3p AO of aluminum with the 2p , AO of bridging fluorine atoms . In this case , 2p . ( F ) -3p , ( Al ) interaction in the bridging bond becomes weaker compared to that in the isolated ...
Trang 1416
... bridging and terminal bonds is no more than 0.05 Å . By contrast , in LSH ( 3 ) hexahy- drides with weaker S - H bonds , the bridging S - H , bond is ca. 0.35 Å longer than the terminal S - H , bond ; i.e. , it is nearly ruptured . The ...
... bridging and terminal bonds is no more than 0.05 Å . By contrast , in LSH ( 3 ) hexahy- drides with weaker S - H bonds , the bridging S - H , bond is ca. 0.35 Å longer than the terminal S - H , bond ; i.e. , it is nearly ruptured . The ...
Trang 1418
... bridging F atom remains in the SF6 fragment , and , in the hydride LSH ions , the H atom leaves the SH fragment and approaches the cation to form the LH · SH , structure . Χ F Χ F = X F = 47 , Using this line of reasoning , we may ...
... bridging F atom remains in the SF6 fragment , and , in the hydride LSH ions , the H atom leaves the SH fragment and approaches the cation to form the LH · SH , structure . Χ F Χ F = X F = 47 , Using this line of reasoning , we may ...
Nội dung
Synthesis and Properties of Inorganic Compounds | 1301 |
Xray Diffraction Study of LnMn2O5 5 Ln La Nd M Ca Ba LIBRARY | 1308 |
Synthesis of MolybdenumIV Oxide in Lithium ChloridePotassium Chloride EutecticMelts | 1317 |
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absorption according acid addition analysis angle anions aqueous atoms band bond bridging calculated cation changes charge Chem chemical Chemistry chloride cm-¹ complexes composition compounds concentration constant containing coordination Copyright corresponding crystal curves decomposition decrease derivatives described determined diagram distances effect electron energy enthalpies experimental extraction formation frequencies H₂O heating higher hydrogen increase indicates initial Inorganic intensity interaction ions Khim kJ/mol ligand measured melt metal method mixed mixture mol/l molecules Moscow Neorg observed obtained occur oxide oxygen parameters phase phosphate positions powder prepared presented properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples shift shows similar sodium solid solution space group spectra spectrum stability structure studied synthesis Table temperature thermal tion Translation unit values vibrations X-ray diffraction