Russian Journal of Inorganic Chemistry, Tập 47,Trang 453-936British Library Lending Division with the cooperation of the Royal Society of Chemistry, 2002 |
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Trang 473
... redox stability are considered , and a classification of oxidation states is presented . It is demonstrated that the nature of the central ion and the relationships between the properties of the central ion and the ligands are of ...
... redox stability are considered , and a classification of oxidation states is presented . It is demonstrated that the nature of the central ion and the relationships between the properties of the central ion and the ligands are of ...
Trang 474
... redox potentials are assumed to be the main criterion for the stability of redox systems . They are determined by the equilibrium electromotive force of a galvanic cell consisting of redox and standard ( e.g. , hydrogen ) half - cells ...
... redox potentials are assumed to be the main criterion for the stability of redox systems . They are determined by the equilibrium electromotive force of a galvanic cell consisting of redox and standard ( e.g. , hydrogen ) half - cells ...
Trang 482
... redox couples systematically exhibit more positive potentials than their tungsten analogues . The potential shift is 0.1 V for fluorides and in the range from 0.53 V for the [ MC14 ( N3S2 ) ] ̄ / [ MC14 ( N3S2 ) ] 2 ̄ cou- ple to 0.87 V ...
... redox couples systematically exhibit more positive potentials than their tungsten analogues . The potential shift is 0.1 V for fluorides and in the range from 0.53 V for the [ MC14 ( N3S2 ) ] ̄ / [ MC14 ( N3S2 ) ] 2 ̄ cou- ple to 0.87 V ...
Nội dung
Vol 47 No 4 | 453 |
Physicochemical Aspects of the Synthesis of MercuryCopper Mixed Oxide Superconductors | 464 |
On the Stabilization of Oxidation States upon Coordination | 473 |
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Academy of Sciences acid actinides Akad amide ampule anions annealing bond calculated cations charge chelates Chem chemical Chuvaev clusters cm-¹ complexes composition concentration coordination compounds corresponding crystal curves decomposition decrease defects deuterium Dokl electronic electronic configuration elements energy English Translation Copyright enthalpy equilibrium experimental formation gallium hydrated hydrogen increase Inorg Inorganic Chemistry interaction ionic Ionova ions iron(II KBBO Khim kJ/mol lanthanides ligands MAIK Nauka/Interperiodica melt metal method MgB2 molecular Moscow Moscow State University Nauk SSSR Neorg Original Russian Text oxidation oxygen oxygen atoms parameters phase Phys Physics plexes potential properties proton radioactive reaction redox Russia Received Russian Academy Russian Journal Russian Text Copyright sample scandium sodium solid solutions spectra spectrum Spitsyn stability structure studied superconducting synthesis Table technetium temperature thermal tion transition unit cell values water molecules X-ray diffraction