Russian Journal of Inorganic Chemistry, Tập 47,Trang 453-936British Library Lending Division with the cooperation of the Royal Society of Chemistry, 2002 |
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Trang 481
... ligands were formulated in [ 1 ] as follows : 11 ( 1 ) Lower oxidation states are preferably stabilized by ligands that decrease the electronegativity of the metal atom . These ligands ' must have free orbitals which can accept excess ...
... ligands were formulated in [ 1 ] as follows : 11 ( 1 ) Lower oxidation states are preferably stabilized by ligands that decrease the electronegativity of the metal atom . These ligands ' must have free orbitals which can accept excess ...
Trang 489
... ligands . Mixed - Ligand AEE ẞ - Diketonates [ M ( dik ) ¿ Q „ ] In the formation of mixed - ligand complexes of the [ M ( dik ) 2Q , ] type , additional neutral electron - donating ligands Q are introduced into the coordination sphere ...
... ligands . Mixed - Ligand AEE ẞ - Diketonates [ M ( dik ) ¿ Q „ ] In the formation of mixed - ligand complexes of the [ M ( dik ) 2Q , ] type , additional neutral electron - donating ligands Q are introduced into the coordination sphere ...
Trang 490
... ligands , the stronger the bond between the central ion and the " extra " ligands due to the ionic nature of bonds in AEE complexes . When choosing ligands Q that could be involved in the formation of mixed - ligand complexes by reac ...
... ligands , the stronger the bond between the central ion and the " extra " ligands due to the ionic nature of bonds in AEE complexes . When choosing ligands Q that could be involved in the formation of mixed - ligand complexes by reac ...
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Vol 47 No 4 | 453 |
Physicochemical Aspects of the Synthesis of MercuryCopper Mixed Oxide Superconductors | 464 |
On the Stabilization of Oxidation States upon Coordination | 473 |
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absorption acid actinides activity addition Akad analysis anions annealing atoms band bismuth bond calculated cations charge Chem chemical Chemistry clusters complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease defects depends determined diffraction effect electronic elements energy equilibrium et al example exist experimental field formation function heating higher hydrated hydrogen increase Inorganic Institute interaction ions Journal Khim ligands materials measured melt metal method mixed molecules Moscow Nauk Neorg observed obtained oxidation oxygen parameters phase Phys Physics positions possible potential prepared presence pressure properties range ratio reaction reduced respectively Russian sample Sciences shift showed similar solid solid solutions solutions space group spectra spectrum Spitsyn stability structure studied synthesis Table technetium temperature thermal tion transition unit values X-ray