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Trang 479
... the absence of ligand field effects ( e.g. , caused by differences in crystal field stabi- lization energies ) . ... electrons for different elements [ 23 ] . by the electrostatic part of the crystal field potential , which varies ...
... the absence of ligand field effects ( e.g. , caused by differences in crystal field stabi- lization energies ) . ... electrons for different elements [ 23 ] . by the electrostatic part of the crystal field potential , which varies ...
Trang 499
However , the one - zone anneal has the following drawback : it is suitable only for syn- thesis of phases whose compositions correspond to the boundaries of the homogeneity field . Variant II . This is a nonisothermal variant of the ...
However , the one - zone anneal has the following drawback : it is suitable only for syn- thesis of phases whose compositions correspond to the boundaries of the homogeneity field . Variant II . This is a nonisothermal variant of the ...
Trang 612
As a first approximation , the enthalpy of mixing can be estimated based on the splitting of the terms of the substituent ion in the ligand field . For oxygen com- pounds of high - valence iron , manganese , chromium , and other metals ...
As a first approximation , the enthalpy of mixing can be estimated based on the splitting of the terms of the substituent ion in the ligand field . For oxygen com- pounds of high - valence iron , manganese , chromium , and other metals ...
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Vol 47 No 4 | 453 |
Physicochemical Aspects of the Synthesis of MercuryCopper Mixed Oxide Superconductors | 464 |
On the Stabilization of Oxidation States upon Coordination | 473 |
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absorption acid actinides activity addition Akad analysis anions annealing atoms band bismuth bond calculated cations charge Chem chemical Chemistry clusters complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease defects depends determined diffraction effect electronic elements energy equilibrium et al example exist experimental field formation function heating higher hydrated hydrogen increase Inorganic Institute interaction ions Journal Khim ligands materials measured melt metal method mixed molecules Moscow Nauk Neorg observed obtained oxidation oxygen parameters phase Phys Physics positions possible potential prepared presence pressure properties range ratio reaction reduced respectively Russian sample Sciences shift showed similar solid solid solutions solutions space group spectra spectrum Spitsyn stability structure studied synthesis Table technetium temperature thermal tion transition unit values X-ray