Russian Journal of Inorganic Chemistry, Tập 47,Trang 453-936British Library Lending Division with the cooperation of the Royal Society of Chemistry, 2002 |
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Trang 519
... energy ( line 2 in Figs . 1a , 1b ) . As mentioned above , this is likely a result of the localization of an electron in a d orbital of these ions upon coordination , so that their fd excitation energy is lower than the d - level ...
... energy ( line 2 in Figs . 1a , 1b ) . As mentioned above , this is likely a result of the localization of an electron in a d orbital of these ions upon coordination , so that their fd excitation energy is lower than the d - level ...
Trang 521
... energy is lower than the d - level stabilization energy . Figure 3 shows the plots of hydration energy of Ln2 + and Ln3 + versus atomic number Z. Straight line 1A cor- responds to the dependence of the hydration energy on Z for Ln2 + ...
... energy is lower than the d - level stabilization energy . Figure 3 shows the plots of hydration energy of Ln2 + and Ln3 + versus atomic number Z. Straight line 1A cor- responds to the dependence of the hydration energy on Z for Ln2 + ...
Trang 660
... energy of a metal varies with the interatomic distance as the metal is heated or compressed . The bond energy is estimated as a function of bond length for binary crystalline compounds . Table 1. n values in the relationship E = Ald.
... energy of a metal varies with the interatomic distance as the metal is heated or compressed . The bond energy is estimated as a function of bond length for binary crystalline compounds . Table 1. n values in the relationship E = Ald.
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Vol 47 No 4 | 453 |
Physicochemical Aspects of the Synthesis of MercuryCopper Mixed Oxide Superconductors | 464 |
On the Stabilization of Oxidation States upon Coordination | 473 |
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absorption acid actinides activity addition Akad analysis anions annealing atoms band bismuth bond calculated cations charge Chem chemical Chemistry clusters complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease defects depends determined diffraction effect electronic elements energy equilibrium et al example exist experimental field formation function heating higher hydrated hydrogen increase Inorganic Institute interaction ions Journal Khim ligands materials measured melt metal method mixed molecules Moscow Nauk Neorg observed obtained oxidation oxygen parameters phase Phys Physics positions possible potential prepared presence pressure properties range ratio reaction reduced respectively Russian sample Sciences shift showed similar solid solid solutions solutions space group spectra spectrum Spitsyn stability structure studied synthesis Table technetium temperature thermal tion transition unit values X-ray