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Upon an increase in pH , all ligand molecules coordinate to indium . Regardless of the acidity of the solution , DTPA acts as an octadentate ligand in the In3 + complexes ; at low pH , the coordination number eight is accomplished due ...
Upon an increase in pH , all ligand molecules coordinate to indium . Regardless of the acidity of the solution , DTPA acts as an octadentate ligand in the In3 + complexes ; at low pH , the coordination number eight is accomplished due ...
Trang 1137
These deviations are due to the difference in the donor - acceptor properties of chelating ligands . . . Peculiarities of the formation of mixed - ligand cop- the formation of the higher homoleptic and mixed per complexes containing ...
These deviations are due to the difference in the donor - acceptor properties of chelating ligands . . . Peculiarities of the formation of mixed - ligand cop- the formation of the higher homoleptic and mixed per complexes containing ...
Trang 1235
For example , in complex 3 , intramolecular hydrogen bonds and adopts a planar the O ( 1 ) atom of the Ipa2- ligand is more electronega- trans configuration ( Fig . 1 ) . In such conformation , the tive than the N atom of the same ...
For example , in complex 3 , intramolecular hydrogen bonds and adopts a planar the O ( 1 ) atom of the Ipa2- ligand is more electronega- trans configuration ( Fig . 1 ) . In such conformation , the tive than the N atom of the same ...
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Vol 40 No 7 | 1021 |
Synthesis of LaCuNi 025+ 8 from Carboxylates | 1030 |
A A Andreev M F Bulanyi S A Golikov and L A Mozharovskii | 1039 |
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absorption Academy of Sciences according acid activity addition analysis angles anion aqueous atoms bands bond calculated cation cell changes Chem chemical Chemistry complexes composition compounds concentration constants containing coordination copper Copyright corresponding crystals curves decomposition decrease dependence described determined distances effect electron energy equilibrium experimental extraction fact fluoride formation groups heating hydrogen increase indicates initial Inorganic Institute intensity interaction ions Khim ligand lines melt metal method mixture molecules Moscow Neorg Note observed obtained occurs oxide oxygen parameters phase position powder prepared presented pressure properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples shift shows similar sodium solid solubility solutions spectra spectrum stability structure studied synthesis Table temperature tetrahedral thermal tion Translation values vibrations X-ray diffraction