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It is established that , in the course of thermal decomposition , these complexes are disproportionate with the formation of Re ( CO ) , CI and ReO2 , i.e. , the low - temperature split of the metal - metal bond occurs .
It is established that , in the course of thermal decomposition , these complexes are disproportionate with the formation of Re ( CO ) , CI and ReO2 , i.e. , the low - temperature split of the metal - metal bond occurs .
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The decomposition of the peroxo solvates normally occurs simultaneously in two directions : - mM " * AM + nH2O2 > m + m) MM * [ A ... ( H2O2 ) , ] "nH2O + žno ,, ( 1 ) M " * " + nH , 0 + žno2 .
The decomposition of the peroxo solvates normally occurs simultaneously in two directions : - mM " * AM + nH2O2 > m + m) MM * [ A ... ( H2O2 ) , ] "nH2O + žno ,, ( 1 ) M " * " + nH , 0 + žno2 .
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The oxygen exchange between oxochloro and oxygen anions involving the 180 isotope was studied in order to elucidate the mechanism of decomposition . b . 2 . EXPERIMENTAL Sodium perchlorate and chlorate were twice crystallized from water ...
The oxygen exchange between oxochloro and oxygen anions involving the 180 isotope was studied in order to elucidate the mechanism of decomposition . b . 2 . EXPERIMENTAL Sodium perchlorate and chlorate were twice crystallized from water ...
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absorption Abstract according acid amount analysis anion appearance aqueous solutions atoms band bismuth bond calculated cations Chem chemical Chemistry chloride complexes composition compounds concentration constants containing coordination Copyright corresponding crystals curves decomposition decrease dependence described determined diagram effect electronic energy equation equilibrium experimental formation groups heating higher hydrogen increase indicates initial Inorganic intensity interaction ionic ions Khim ligand measured melting metal method mixture mol/l molecules Moscow Neorg Note observed obtained occurs oxide oxygen parameters particles phase positions powder diffraction precipitate prepared present properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples Sciences shows similar sodium solid solubility solutions solvent space group spectra spectrum stability structure studied synthesis Table temperature thermal tion Translation values vibrations X-ray powder