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The P - C bond lengths in the triphenylphosphine ligand are 1.84 ( 1 ) , 1.83 ( 1 ) , and 1.82 ( 1 ) Å . As is normal , the Au - P - C type bond angles ( 113.7 , 112.3 , and 115.5 ° ) are larger , and the C - P - C type angles ( 103.8 ...
The P - C bond lengths in the triphenylphosphine ligand are 1.84 ( 1 ) , 1.83 ( 1 ) , and 1.82 ( 1 ) Å . As is normal , the Au - P - C type bond angles ( 113.7 , 112.3 , and 115.5 ° ) are larger , and the C - P - C type angles ( 103.8 ...
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3 It was previously shown for mercury compounds that the strength of the secondary bond M ... X increases ( the distance decreases ) with increase in the nucleophilic character of the heteroatom X involved in the secondary bond .
3 It was previously shown for mercury compounds that the strength of the secondary bond M ... X increases ( the distance decreases ) with increase in the nucleophilic character of the heteroatom X involved in the secondary bond .
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This indicates a hyperbolic relationship , typical of secondary bonds , between the two distances , one of which corresponds to the principal bond , and the other to a secondary bond ( the limit corresponds to inversion of the bonds ...
This indicates a hyperbolic relationship , typical of secondary bonds , between the two distances , one of which corresponds to the principal bond , and the other to a secondary bond ( the limit corresponds to inversion of the bonds ...
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