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Trang S-42
The W - O ( L ' ) bond ( 2.12 ( 1 ) Å ) is longer than the typical values and falls in the lower boundary of the broad range of W - O ( L ) trans bond lengths in monomeric octahedral W ( VI ) monooxo complexes ( 2.12-2.34 Å , see Table ...
The W - O ( L ' ) bond ( 2.12 ( 1 ) Å ) is longer than the typical values and falls in the lower boundary of the broad range of W - O ( L ) trans bond lengths in monomeric octahedral W ( VI ) monooxo complexes ( 2.12-2.34 Å , see Table ...
Trang S-46
onal arrangement of the three chloro ligands , the trans position relative to the oxo ligand is occupied , in accor- dance with the SCR , by the neutral electron - donating end of the bidentate chelating ligand , namely , the O ( 1 ) ...
onal arrangement of the three chloro ligands , the trans position relative to the oxo ligand is occupied , in accor- dance with the SCR , by the neutral electron - donating end of the bidentate chelating ligand , namely , the O ( 1 ) ...
Trang S-47
The W - NH bond ( 2.26 Å ) , which is trans to W = Ooxo , is substantially ( by 0.43 Å ) longer than the W - N multiple bond ( 1.83 ( 1 ) Å ) . In the [ WC1 , ( N3S2 ) ] ̄ complex [ 39 ] , containing deprotonated N3S2 ligand , the W = N ...
The W - NH bond ( 2.26 Å ) , which is trans to W = Ooxo , is substantially ( by 0.43 Å ) longer than the W - N multiple bond ( 1.83 ( 1 ) Å ) . In the [ WC1 , ( N3S2 ) ] ̄ complex [ 39 ] , containing deprotonated N3S2 ligand , the W = N ...
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Vol 45 Suppl 1 | S-2 |
Effect of Defects on Electronic Structure Chemical Bonding | S-3 |
Conclusions | S-30 |
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addition analysis angle anions atoms band bond calculated cations characteristics characterized Chem chemical Chemistry close complexes composition compounds concentration conductivity considerable considered containing coordination corresponding crystal curves decrease defects density dependence described determined diffusion direct distance distribution domain effect electron elements energy example existence faces fluorides formation given groups impurity increase influence Inorganic interactions interatomic involved ionic Journal lattice layer ligand magnetic Mater melting metal method molecules nature Neorg nitride Note observed occur overlap oxide oxygen packing parameters phase Phys Physics polyhedron positions possible processes properties radii range reaction region respectively rule Russian shift shows similar single solid solutions space space group spectra sphere stability structure studied surface Table temperature tion topological trans transition unit vacancies values VD polyhedra