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Trang S-37
Structural Chemistry of Mononuclear Six - Coordinate Tungsten ( VI ) Oxo Complexes V. S. Sergienko Kurnakov Institute of General and Inorganic Chemistry , Russian Academy of Sciences , Leninskii pr . 31 , Moscow , 117907 Russia Abstract ...
Structural Chemistry of Mononuclear Six - Coordinate Tungsten ( VI ) Oxo Complexes V. S. Sergienko Kurnakov Institute of General and Inorganic Chemistry , Russian Academy of Sciences , Leninskii pr . 31 , Moscow , 117907 Russia Abstract ...
Trang S-48
Unlike W ( VI ) com- fragments , where Hal is fluorine in one complex and plexes XXXI and XXXIII in which the trans - effect of chlorine in the other seven complexes . Seven of the the alkylidene ligand is manifested to a somewhat eight ...
Unlike W ( VI ) com- fragments , where Hal is fluorine in one complex and plexes XXXI and XXXIII in which the trans - effect of chlorine in the other seven complexes . Seven of the the alkylidene ligand is manifested to a somewhat eight ...
Trang S-62
increase on passing from mono- to dioxo complexes , 8 structures , respectively ) are , on the average , 0.026 , on the average , by 0.048 and 0.153 Å ( from 1.890 to 0.005 , and 0.040 Å shorter than the corresponding 1.938 Å and from ...
increase on passing from mono- to dioxo complexes , 8 structures , respectively ) are , on the average , 0.026 , on the average , by 0.048 and 0.153 Å ( from 1.890 to 0.005 , and 0.040 Å shorter than the corresponding 1.938 Å and from ...
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Effect of Defects on Electronic Structure Chemical Bonding | S-3 |
Contents | S-16 |
Conclusions | S-30 |
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addition analysis angle anions atoms average band bond calculated cations characteristics characterized Chem chemical Chemistry close complexes composition compounds concentration conductivity considerable considered containing coordination corresponding crystal curves decrease defects density dependence described determined diffusion direct distance distribution domain effect electron elements energy example existence faces fluorides formation given groups impurity increase influence Inorganic interactions interatomic involved ionic Journal lattice layer ligand magnetic materials melting metal method molecules nature nitride Note observed occur overlap oxide oxygen packing parameters phase Phys Physics polyhedron positions possible processes properties radii range reaction region respectively rule Russian shift shows similar single solid solutions space space group spectra sphere stability structure studied surface Table temperature tion topological trans transition unit vacancies values VD polyhedra