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In addition to the trans The bond lengths Re - O ( OPR3 ) ( trans ) are 2.063 Å isomer ( a ) , we have also obtained a cis - facial isomer ( A ' = 0.023 Å ) and 2.053 Å ( A ' = 0.013 Å ) in the struc( b ) of this crystalline compound ...
In addition to the trans The bond lengths Re - O ( OPR3 ) ( trans ) are 2.063 Å isomer ( a ) , we have also obtained a cis - facial isomer ( A ' = 0.023 Å ) and 2.053 Å ( A ' = 0.013 Å ) in the struc( b ) of this crystalline compound ...
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L2 complexes ; relative intensities of lines are in parentheses ( eq is equatorial , ax is axial Br atom ) Ligand L ( isomer ) T , K v ( 8'Br ) , MHz UM Assignment References TMU ( trans ) 77 0.389 Sn - Breg 0.384 0.384 300 125.300 ( 2 ) ...
L2 complexes ; relative intensities of lines are in parentheses ( eq is equatorial , ax is axial Br atom ) Ligand L ( isomer ) T , K v ( 8'Br ) , MHz UM Assignment References TMU ( trans ) 77 0.389 Sn - Breg 0.384 0.384 300 125.300 ( 2 ) ...
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tr 1 - - . perrhenate complexes ( X and XI ) , the angle distor- tion - active centers , the trans position to O ( oxo ) is occutions of the coordination polyhedra are rather high : pied by the former ( the phenol O atom , rather than ...
tr 1 - - . perrhenate complexes ( X and XI ) , the angle distor- tion - active centers , the trans position to O ( oxo ) is occutions of the coordination polyhedra are rather high : pied by the former ( the phenol O atom , rather than ...
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absorption Abstract According acid addition analysis angles anions appearance aqueous atoms band bonds calculated cations Chem chemical Chemistry chloride compared complexes components composition compounds concentration constants containing coordination Copyright corresponding crystal curves decomposition decrease dependence described determined distances effect electron elements energy equation equilibrium exhibit experimental extraction formation heating hydrogen increase indicates initial Inorganic intensity interaction ions Khim leads ligand measured melting metal method mixture mol/l molecules Moscow Neorg Note observed obtained Original oxide oxygen parameters patterns phase points position possible powder precipitate prepared present properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples shows similar sodium solid solutions space group spectra spectrum stability structure studied synthesis Table temperature thermal tion trans Translation values various vibrations X-ray diffraction