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During H - D isotopic sub- stitution , this band shifts by 160 cm - 1 to the low - fre- quency range ( Figs . 2 and 6 , Table 3 ) . This shift is close to a theoretical value of VH / VD 21/2 . Therefore , this band was assigned to the ...
During H - D isotopic sub- stitution , this band shifts by 160 cm - 1 to the low - fre- quency range ( Figs . 2 and 6 , Table 3 ) . This shift is close to a theoretical value of VH / VD 21/2 . Therefore , this band was assigned to the ...
Trang 1421
Because of their accidental superposition , the base atoms are strongly bonded to the metal cation two vibrations are manifested in the spectra of free ligands by a single intense band with the maximum at 1670-1660 cm - 1 .
Because of their accidental superposition , the base atoms are strongly bonded to the metal cation two vibrations are manifested in the spectra of free ligands by a single intense band with the maximum at 1670-1660 cm - 1 .
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As is seen in Table 4 , the spectrum of POF3 contains about 30 uniquely assigned bands corresponding to transi- tions with the total vibrational quantum number v≤3 . Note that we did not observe the band at 1275 cm - 1 reported in [ 24 ] ...
As is seen in Table 4 , the spectrum of POF3 contains about 30 uniquely assigned bands corresponding to transi- tions with the total vibrational quantum number v≤3 . Note that we did not observe the band at 1275 cm - 1 reported in [ 24 ] ...
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absorption Abstract According acid analysis angles anions appearance aqueous atoms band bonds calculated cations Chem chemical Chemistry chloride cm-¹ compared complexes components composition compounds concentration constants containing coordination Copyright corresponding crystal curves decomposition decrease dependence described determined distances effect electron elements energy equation equilibrium exhibit experimental extraction formation H₂O heating hydrogen increase indicates initial Inorganic intensity interaction ions Khim leads ligand measured melting metal method mixture mol/l molecules Moscow Neorg Note observed obtained Original oxide oxygen parameters patterns phase points position possible powder precipitate prepared present properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples shows similar sodium solid solutions space group spectra spectrum stability structure studied synthesis Table temperature thermal tion trans Translation values various vibrations X-ray diffraction