Russian Journal of Inorganic Chemistry, Tập 29,Số phát hành 1-6British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1984 |
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Trang 282
... fluorides demonstrated , and the trends in the pyrohydrolysis of inorganic fluorides described in the light of the periodic law and work of D.I.Mendeleev . The chemistry of the fluorides - an extensive class of com- pounds confirms ...
... fluorides demonstrated , and the trends in the pyrohydrolysis of inorganic fluorides described in the light of the periodic law and work of D.I.Mendeleev . The chemistry of the fluorides - an extensive class of com- pounds confirms ...
Trang 285
... fluorides of the elements of groups IV - VII are much lower than those of the transition metal fluorides . The change in the standard entropy of the higher fluo- rides of the transition metals is typically monotonic ( Fig.3 ) . A ...
... fluorides of the elements of groups IV - VII are much lower than those of the transition metal fluorides . The change in the standard entropy of the higher fluo- rides of the transition metals is typically monotonic ( Fig.3 ) . A ...
Trang 286
... fluorides of the transition metals , the maximum corresponds to the trifluorides , LaF , being the most stable ( AG ° = 75.8 kcal mole ̄1 ) . It has also been pointed out 60 that all volatile fluorides can undergo hydrolysis ...
... fluorides of the transition metals , the maximum corresponds to the trifluorides , LaF , being the most stable ( AG ° = 75.8 kcal mole ̄1 ) . It has also been pointed out 60 that all volatile fluorides can undergo hydrolysis ...
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absorption acid actinides Akad alkali metal analysis anion aqueous solutions bands bond calculated cations Chem chemical chloride cm¹ complex formation composition compounds concentration constants coordination corresponding crystal crystallisation curves D.I.Mendeleev decrease determined electronic elements energy equilibrium europium experimental Figure fluorides formed gallium germanium H₂O heating hydration hydride hydrogen increase infrared infrared spectra Inorg interaction investigated ionic ions iron(III jarosite kcal Khim Khimiya lanthanide lattice ligands liquid manganese(III melts Mendeleev method mole mole¹ molybdenum Moscow Nauk SSSR Neorg observed obtained oxide oxygen parameters Periodic Law Periodic System phase Phys platinum(II potassium precipitate properties proton range ratio reaction Russ salts shows sodium solid solutions solubility specimens spectrum stability structure studied substances synthesis Table temperature thermodynamic tion transition metal Translated from Zhurnal Translated into Russian values vanadium vanadium(V wavenumbers X-ray diffraction Zhur Zhur.Neorg Zhurnal Neorganicheskoi Khimii