Russian Journal of Inorganic Chemistry, Tập 40,Trang 511-1020Chemical Society., 1995 |
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... atoms , including heteroatoms . The reorganiza- tion energies on passing from a free reagent to the ligands in these complexes can be so great that they determine both the energetics of the process and the structure of a central atom ...
... atoms , including heteroatoms . The reorganiza- tion energies on passing from a free reagent to the ligands in these complexes can be so great that they determine both the energetics of the process and the structure of a central atom ...
Trang 930
In the complexes with multidentate ligands , the polyhedra of central atoms are always distorted to a greater or ... atom situated in one of the polyhedron vertices , into a distorted antiprism and then into a seven - coordi- nation ...
In the complexes with multidentate ligands , the polyhedra of central atoms are always distorted to a greater or ... atom situated in one of the polyhedron vertices , into a distorted antiprism and then into a seven - coordi- nation ...
Trang 934
... central atom of a complex . As noted , a minimum gap between the mixing levels is required . For the metal complexes , these are the excited levels of the central atoms or MOS with an essential contribution of the AOS of the central atom ...
... central atom of a complex . As noted , a minimum gap between the mixing levels is required . For the metal complexes , these are the excited levels of the central atoms or MOS with an essential contribution of the AOS of the central atom ...
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Vol 40 No 4 | 511 |
Synthesis and Thermal Stability of Praseodymium Triiodide and Oxoiodide | 519 |
Interaction of Strontium Chloride with NiobiumV Oxide | 527 |
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absorption Academy of Sciences acid Akad analysis angles anion aqueous solutions band bond lengths calculated cations central atom Chem chemical chloride cm-¹ coefficients complex components composition compounds concentration coordination coordination sphere corresponding crystal curve decomposition decrease determined electrolyte electron energy English Translation Copyright enthalpies equation equilibrium europium eutectic experimental extraction formation H₂O Hayka/Interperiodica Publishing Russia heating hydrated hydride hydrogen increase Inorg interaction ionic ions iron(III isomer kcal/mol Khim kJ/mol ligand liquidus luminophor melting metal method mixture mol/l Moscow Nauk SSSR Neorg observed obtained Original Russian Text osmium oxidation oxygen atoms parameters peritectic phase diagram podands properties range ratio region ruled surfaces Russia Received Russian Academy Russian Text Copyright salts sample scandium sodium solid phase solid solutions sorbent spectra spectrum stability structure studied surface synthesis Table temperature tetrahedra thermal thermodynamic tion values vibrations X-ray diffraction X-ray powder diffraction yttrium