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The significant effect of the solvents on the complex stability was shown . The dependence of the stability of the complex between NHM and 18 - crown - 6 on the nature of the solvent is estimated in terms of the dielectric constant and ...
The significant effect of the solvents on the complex stability was shown . The dependence of the stability of the complex between NHM and 18 - crown - 6 on the nature of the solvent is estimated in terms of the dielectric constant and ...
Trang 129
Effect of the solvent properties ( E , DN ) on the values of the stability constants of the complex NH - 18 - crown - 6 Gutmann E donor log Kg Solvent ( at 25 ° C ) number NH - 18 - crown - 6 ( DN ) Ethanol 24.3 30.0 2.91 Acetonitrile ...
Effect of the solvent properties ( E , DN ) on the values of the stability constants of the complex NH - 18 - crown - 6 Gutmann E donor log Kg Solvent ( at 25 ° C ) number NH - 18 - crown - 6 ( DN ) Ethanol 24.3 30.0 2.91 Acetonitrile ...
Trang 331
Logarithms of the total stability constants for the distribution constant Bi ( TU ) * complexes in aqueous solutions at 295 + 1 K p = D / a , CTUCA HCIO4 HNO3 + NaNO ; at Ca- = const yield the plot of log ( D / 00 ) versus log CTU i ...
Logarithms of the total stability constants for the distribution constant Bi ( TU ) * complexes in aqueous solutions at 295 + 1 K p = D / a , CTUCA HCIO4 HNO3 + NaNO ; at Ca- = const yield the plot of log ( D / 00 ) versus log CTU i ...
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absorption Abstract According acid addition analysis angles anion aqueous atoms bands bismuth bonds calculated carbon carried cations Chem chemical Chemistry complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease dependence described determined distances effect electron elements energy exhibit experimental extraction formation formed heating hydrogen increase indicates initial Inorganic Institute intensity interaction ions Khim lattice leads ligand measured metal method mixture mol/l molecules Moscow Neorg Note observed obtained occurs organic oxide oxygen parameters phase positions possible powder prepared presence pressure properties Publishing range rare-earth ratio reaction REFERENCES region respectively Russian salts samples Sciences shift shows similar solid solubility solution sorbents space group spectra spectrum stability structure studied synthesis Table temperature thermal tion transition Translation values various vibrations X-ray diffraction