Russian Journal of Inorganic Chemistry, Tập 43,Trang 1471-1805Chemical Society., 1998 |
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Trang 1557
... sulfur electronic state in the series H2S- ( CH3 ) 2S - B10H12 [ S ( CH3 ) 2 ] 2 is compared with the electronic state of sulfur in the thia- borane arachno - B9SH12 cluster . In both the B10H12 [ S ( CH3 ) 2 ] 2 compound and the B9SH12 ...
... sulfur electronic state in the series H2S- ( CH3 ) 2S - B10H12 [ S ( CH3 ) 2 ] 2 is compared with the electronic state of sulfur in the thia- borane arachno - B9SH12 cluster . In both the B10H12 [ S ( CH3 ) 2 ] 2 compound and the B9SH12 ...
Trang 1558
... sulfur ( ca. 90 % as predicted by MNDO ) . Therefore , considering this orbital to be a lone electron pair is rather conventional . In the SKB spectrum , the strongest line corresponds to the 26 orbital , which is evidence for the major ...
... sulfur ( ca. 90 % as predicted by MNDO ) . Therefore , considering this orbital to be a lone electron pair is rather conventional . In the SKB spectrum , the strongest line corresponds to the 26 orbital , which is evidence for the major ...
Trang 1560
... sulfur atom and the boron atoms when going from B10H12 [ S ( CH3 ) 2 ] 2 to B9SH12 , i.e. , to the compound where the sulfur atom is directly inserted in the borane cluster . Its structure and topological scheme are shown in Fig . 1 ...
... sulfur atom and the boron atoms when going from B10H12 [ S ( CH3 ) 2 ] 2 to B9SH12 , i.e. , to the compound where the sulfur atom is directly inserted in the borane cluster . Its structure and topological scheme are shown in Fig . 1 ...
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Synthesis and Properties of Inorganic Compounds | 1471 |
Synthesis and Structure of Ternary Calcium Lithium and Copper Phosphate CaCuLiPO47 | 1481 |
Stabilized Solid Solutions Based on Complex Oxide Lanthanide Compounds Ln14GeO42BO36O8 | 1488 |
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absorption according acid addition analysis angle anion aqueous solution atoms band bond calculated cations changes Chem chemical Chemistry chloride cluster cm-¹ complex composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease derivatives described determined effect electron energy enthalpies equal equation exchange experimental extraction formation H₂O heating higher hydrates hydrogen increase indicates initial Inorganic interaction ions Journal Khim kJ/mol ligand measured melt metal method mixed mixtures mol/l molecules Moscow Neorg observed obtained occur oxides oxygen parameters phase podands positions powder prepared presence Publishing range ratio reaction REFERENCES respectively Russian salts samples Sciences shift shows similar sodium solid solutions solutions solvent space group species spectra spectrum standard structure studied substitution sulfur synthesis Table temperature thermal tion Translation values vibrations X-ray diffraction