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A thermodynamic and kinetic analysis of the solution of CuO and YBa1⁄2Cu3O7 – x in hydrochloric acid has shown that the oxide phase CuO can disproportionate according to the scheme 2CuO ( solid ) + [ CuP * ( solid ) ] + [ CuO ̄ ( solid ) ...
A thermodynamic and kinetic analysis of the solution of CuO and YBa1⁄2Cu3O7 – x in hydrochloric acid has shown that the oxide phase CuO can disproportionate according to the scheme 2CuO ( solid ) + [ CuP * ( solid ) ] + [ CuO ̄ ( solid ) ...
Trang 1357
At low and high acid concentrations , the concentration of copper ( I ) ions is sufficient to remove the excess oxygen formed by the disproportionation of copper ( II ) oxides and the accumulation of CuO ions in the solid phase ( Table ...
At low and high acid concentrations , the concentration of copper ( I ) ions is sufficient to remove the excess oxygen formed by the disproportionation of copper ( II ) oxides and the accumulation of CuO ions in the solid phase ( Table ...
Trang 1360
solution stage : [ CuOOH 02 solid ] + ( Cu ) * ↔ [ Cu TM −O − O - Cusolid ] ⇒CuOH ++ 03 + other solution products ( 4 ) The limiting stage is the transfer of CuOH * from the solid intermediate complex to the solution ; the rate of ...
solution stage : [ CuOOH 02 solid ] + ( Cu ) * ↔ [ Cu TM −O − O - Cusolid ] ⇒CuOH ++ 03 + other solution products ( 4 ) The limiting stage is the transfer of CuOH * from the solid intermediate complex to the solution ; the rate of ...
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Inorganic | 1353 |
Contents | 1376 |
Activation of the solution of copperII oxide in aqueous EDTA solutions by the 1385 2683 | 1385 |
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acid aluminium ammonia analysis angle anions atoms bands bond calculated Chem chemical Chemistry chloride complex formation complexes composition compounds concentration constants containing coordination copper copper(II corresponding crystal crystal structure crystallisation curves decrease dependence described determined diagram dioxide EDTA electronic energy English translation equilibrium experimental Figure formation formed given gives halides heating hydrogen increase indicates influence infrared Inorg INORGANIC ions Khim kinetic ligand manganese(II mass metal method mixture molecular molecules Moscow Neorg observed obtained organic oxide parameters phase positions preparation present properties published range rate of solution reaction respectively salts shows similar solid solubility solution solvate solvents specimens spectra stability structure synthesis Table temperature thermal translation translation in Russ tungsten values vibrational X-ray diffraction