Russian Journal of Inorganic Chemistry, Tập 25,Trang 1-960Chemical Society, 1980 |
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Trang 127
... carbonyl complexes of palladium are erroneous . The interest in the chemistry of carbonyl complexes of Pd is due to a considerable extent to the catalytic properties of Pd compounds in reactions involving CO . The catalytic oxi- dation ...
... carbonyl complexes of palladium are erroneous . The interest in the chemistry of carbonyl complexes of Pd is due to a considerable extent to the catalytic properties of Pd compounds in reactions involving CO . The catalytic oxi- dation ...
Trang 129
... carbonyl molecule contains stabilising ligands , the wavenumber of the VCO stretch is lowered considerably . In the case of the cyano ( carbonyl ) -complex of Pd ° , the infrared active C - O stretch appears at 1790 cm -1 ( phospho ...
... carbonyl molecule contains stabilising ligands , the wavenumber of the VCO stretch is lowered considerably . In the case of the cyano ( carbonyl ) -complex of Pd ° , the infrared active C - O stretch appears at 1790 cm -1 ( phospho ...
Trang 130
... carbonyl halides are comparatively stable to atmospheric oxygen in the absence of H2O . The thermal decomposition of Pd1 carbonyl halides takes place chiefly according to the scheme 2 ( CO ) PDX = Pd + PdX2 + 2CO . ( 5 ) The colour of ...
... carbonyl halides are comparatively stable to atmospheric oxygen in the absence of H2O . The thermal decomposition of Pd1 carbonyl halides takes place chiefly according to the scheme 2 ( CO ) PDX = Pd + PdX2 + 2CO . ( 5 ) The colour of ...
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JOURNAL of V 25 | 1 |
Activities of the Editorial Board | 8 |
COORDINATION obtaining oxides | 15 |
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absorption bands acetonitrile acid Akad alkali metal amines analysis anion aqueous solutions atoms bond calculated carbonyl cation Chem chemical chloride cm-¹ cm¹ cobalt(II complex formation composition concentration containing coordination compounds copper(II corresponding crystallisation crystals curves decrease determined electronic energy enthalpy equilibrium diagram eutectic eutectic point experimental extraction Figure fluoride formed H₂O halides heating hydrogen increase infrared infrared spectra Inorg Inorganic Chemistry interaction investigation ionic ions kcal Khim lanthanide lattice LiBH ligands melt method mixture mole mole¹ molecules Moscow Nauk SSSR Neorg obtained oxidation oxygen parameters pentatope perchlorate perchloric acid phase platinum(II plexes potassium properties protons pyridine range ratio reaction Russ Russ.J salts scandium shows sodium solid solubility specimens spectrum stability constants structure studied synthesis Table temperature ternary tion titanium(IV titration Translated from Zhurnal values vibrational wavenumbers X-ray diffraction Zhur Zhur.Neorg Zhurnal Neorganicheskoi Khimii zirconium