Russian Journal of Inorganic Chemistry, Tập 48,Trang 455-954British Library Lending Division with the cooperation of the Royal Society of Chemistry, 2003 |
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Trang 539
... transition is a ligand - field ( LF ) transition , and the rest are CT transitions [ 8 , 14 , 15 ] . - - The electronic absorption spectra of [ MnO4 ] 2- [ 11 , 13 , 16–18 ] , [ CrO4 ] 3- [ 15 , 19 , 20 ] , and [ VO1 ] + [ 21 , 22 ] in ...
... transition is a ligand - field ( LF ) transition , and the rest are CT transitions [ 8 , 14 , 15 ] . - - The electronic absorption spectra of [ MnO4 ] 2- [ 11 , 13 , 16–18 ] , [ CrO4 ] 3- [ 15 , 19 , 20 ] , and [ VO1 ] + [ 21 , 22 ] in ...
Trang 541
... transition between the states of the ground configuration ; these bands are the beginnings of vibrational ... transition . The assignment of the CT transition bands in the spectra of [ MnO4 ] 3 was reported in [ 11 ] ( Table 4 ) . Note ...
... transition between the states of the ground configuration ; these bands are the beginnings of vibrational ... transition . The assignment of the CT transition bands in the spectra of [ MnO4 ] 3 was reported in [ 11 ] ( Table 4 ) . Note ...
Trang 546
... transition is weaker than the CD band of the 4T1 ( 4F ) 4A2 ( 4F ) transition , due to a considerable negative contribution of the CD band at 25000 cm - 1 associated with the band- to - band transition of the crystal matrix . The best ...
... transition is weaker than the CD band of the 4T1 ( 4F ) 4A2 ( 4F ) transition , due to a considerable negative contribution of the CD band at 25000 cm - 1 associated with the band- to - band transition of the crystal matrix . The best ...
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Vol 48 No 4 | 455 |
Structure of a HighPressure Hydroxide Ta₂O5 23H₂O | 464 |
Synthesis and Physicochemical Properties | 472 |
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absorption According acid activity analysis angles anion aqueous atoms band bismuth bond calculated cations cell Chem chemical Chemistry cm-¹ complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curve decomposition decrease dependence described determined distribution effect electronic energy equilibrium existence experimental extraction field formation formed function H₂O heating higher hydrogen increases Inorganic intensity interactions ionic ions Journal Khim ligand lines measured metal method mixture mol/l molecules Moscow Neorg observed obtained occurs organic oxide oxygen parameters phase Phys Physics points positions prepared presence properties range ratio reaction REFERENCES refinement region respectively Russian salt samples Sciences shift shows solid solubility solutions solvent space group spectra spectrum stability structure studied surface synthesis Table temperature thermal tion transition unit values X-ray diffraction