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The values of the force constants giving satisfactory agreement between the calculated and experimental wavenumbers are listed in Table 2 . Table 3. Wavenumbers of the external vibrations and displacements of the cations in BaзWO6 .
The values of the force constants giving satisfactory agreement between the calculated and experimental wavenumbers are listed in Table 2 . Table 3. Wavenumbers of the external vibrations and displacements of the cations in BaзWO6 .
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For the vibrations of the atoms in the cation sub - lattices , a group - theoretical analysis gives the following ... Thus the Raman spectrum should contain three lines due to vibrations of the highly charged cations , and the infrared ...
For the vibrations of the atoms in the cation sub - lattices , a group - theoretical analysis gives the following ... Thus the Raman spectrum should contain three lines due to vibrations of the highly charged cations , and the infrared ...
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Displacements of the cations in the vibrations . wavenumber ( cm - 1 ) 80 130 158 190 LiLa ( MoO . ) : 285 displacement ( Å ) 0.010 ( Mo ) * 0.010 ( Li ) 0.010 ( La ) 0.005 0.005 0.011 0.002 0.001 0.016 1 0.013 0.001 0.002 wavenumber ...
Displacements of the cations in the vibrations . wavenumber ( cm - 1 ) 80 130 158 190 LiLa ( MoO . ) : 285 displacement ( Å ) 0.010 ( Mo ) * 0.010 ( Li ) 0.010 ( La ) 0.005 0.005 0.011 0.002 0.001 0.016 1 0.013 0.001 0.002 wavenumber ...
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SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS | 1 |
Volume 36 | 4 |
LnO bond lengths in lanthanide compounds with a coordination number of six 15 29 | 15 |
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acid addition analysis angles anion apparently aqueous atoms bands bond bridging calculated carbonate carried cation characteristic Chem chemical Chemistry complexes components composition compounds concentration constant containing coordination corresponding crystallisation crystals curves decomposition decrease dependence described determined dimer distances effect electron energy English translation equilibrium experimental extraction Figure formation formed given gives groups heating hydrogen increase indicate infrared Inorg interaction ions Khim Khimii lanthanide leads ligands lines lower magnetic mass measured metal metal-metal method mixture molecules Moscow Neorg nitrate observed obtained oxide oxygen parameters phase points positions possible precipitate prepared present properties published range ratio reaction References region relative respectively salts shows similar solid solubility solution space group specimens spectra spectrum stability structure studied Table takes temperature thermal translation in Russ values vibrations wavenumbers X-ray diffraction