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The covalent interaction is determined mainly by the overlap of the p - orbitals of the atom A and the 2s - AO of Li . Tables 4 and 5 show that in the octahedral lithides ALi , the first four electron pairs occupy the ag and t1 ...
The covalent interaction is determined mainly by the overlap of the p - orbitals of the atom A and the 2s - AO of Li . Tables 4 and 5 show that in the octahedral lithides ALi , the first four electron pairs occupy the ag and t1 ...
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isomer , the HOMO is either a non - degenerate a1g - orbital , bonding with respect to the interaction of the H atom with the pair of axial atoms Lix and antibonding with respect to the interaction of H with the four equatorial Lieq ...
isomer , the HOMO is either a non - degenerate a1g - orbital , bonding with respect to the interaction of the H atom with the pair of axial atoms Lix and antibonding with respect to the interaction of H with the four equatorial Lieq ...
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When Li is replaced by BeH , this interaction becomes more favourable , the t2g energy is lowered by 0.06 a.u. ... and The structural manifestations of the Be - Be cluster interactions in the " empty " beryllium hydrides BeН are more ...
When Li is replaced by BeH , this interaction becomes more favourable , the t2g energy is lowered by 0.06 a.u. ... and The structural manifestations of the Be - Be cluster interactions in the " empty " beryllium hydrides BeН are more ...
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SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS | 1 |
Volume 36 | 4 |
LnO bond lengths in lanthanide compounds with a coordination number of six 15 29 | 15 |
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acid addition analysis angles anion apparently aqueous atoms bands bond bridging calculated carbonate carried cation characteristic Chem chemical Chemistry complexes components composition compounds concentration constant containing coordination corresponding crystallisation crystals curves decomposition decrease dependence described determined dimer distances effect electron energy English translation equilibrium experimental extraction Figure formation formed given gives groups heating hydrogen increase indicate infrared Inorg interaction ions Khim Khimii lanthanide leads ligands lines lower magnetic mass measured metal metal-metal method mixture molecules Moscow Neorg nitrate observed obtained oxide oxygen parameters phase points positions possible precipitate prepared present properties published range ratio reaction References region relative respectively salts shows similar solid solubility solution space group specimens spectra spectrum stability structure studied Table takes temperature thermal translation in Russ values vibrations wavenumbers X-ray diffraction