Russian Journal of Inorganic Chemistry, Tập 36,Trang 1-922Chemical Society., 1991 |
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... bond will be examined . Firstly , all compounds with a multiple metal - metal bond are coordinationally unsaturated and enter into reactions which lead to an increase in the coordination numbers of the metal atoms . In Cp2M2 ( CO ) 4 ...
... bond will be examined . Firstly , all compounds with a multiple metal - metal bond are coordinationally unsaturated and enter into reactions which lead to an increase in the coordination numbers of the metal atoms . In Cp2M2 ( CO ) 4 ...
Trang 203
... bond in the analogous complex Mo2 ( OBu ' ) , has been found only in one case with the alkyne HC = CPh . These authors 38 attribute the high stability of molybdenum dimers in comparison with tungsten dimers to the weaker reducing power ...
... bond in the analogous complex Mo2 ( OBu ' ) , has been found only in one case with the alkyne HC = CPh . These authors 38 attribute the high stability of molybdenum dimers in comparison with tungsten dimers to the weaker reducing power ...
Trang 205
multiplicity of the metal - metal bond is reduced to a single bond [ r ( Mo - Mo ) 2.720 Å ] .3 = 3 Hydrogen by entering into a redox reaction with the binuclear complex Cp Mo2 ( CO ) 4 ( Cp * = C5Me3 ) reduces the multiplicity of the bond ...
multiplicity of the metal - metal bond is reduced to a single bond [ r ( Mo - Mo ) 2.720 Å ] .3 = 3 Hydrogen by entering into a redox reaction with the binuclear complex Cp Mo2 ( CO ) 4 ( Cp * = C5Me3 ) reduces the multiplicity of the bond ...
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SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS | 1 |
Volume 36 | 4 |
LnO bond lengths in lanthanide compounds with a coordination number of six 15 29 | 15 |
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Thuật ngữ và cụm từ thông dụng
1990 Translated absorption acetonitrile acid aluminium aluminium chloride analysis angles anion atoms bands bond lengths bridging calculated carbonate cation characteristic Chem chemical Chemistry chloride cm-¹ cm¹ composition compounds concentration containing coordination copper(II corresponding crystallisation crystals curves decrease determined dimer DMSO dysprosium electron energy English translation equilibrium experimental Figure formed groups H₂O heating hydrated hydride hydrogen hydroxide increase infrared infrared spectra Inorg interaction ions isomers kcal kcal mol¹ Khim lanthanide ligands lithium magnetic metal metal-metal bonds method mixture molecules molybdenum Moscow Nauka Neorg Neorganicheskoi Khimii 36 nickel(II nitrate NMR spectra obtained oxide oxygen oxygen atoms parameters potassium precipitate present protons range reaction reagent salts scandium singlet sodium solid solutions solubility solvates specimens spectrum structure studied synthesis temperature thermal decomposition Translated from Zhurnal translation in Russ values vibrations wavenumbers X-ray diffraction Zhurnal Neorganicheskoi Khimii