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Trang 824
Obviously , complexes I and II decom- pose under the experimental conditions according to the reaction MnL ( i - Bu2PS2 ) 2 ( s ) Mn ( i - Bu2PS2 ) 2 ( gas ) + L ( gas ) . It should be noted that Mn ( i - Bu2PS2 ) 2 exists in the gas ...
Obviously , complexes I and II decom- pose under the experimental conditions according to the reaction MnL ( i - Bu2PS2 ) 2 ( s ) Mn ( i - Bu2PS2 ) 2 ( gas ) + L ( gas ) . It should be noted that Mn ( i - Bu2PS2 ) 2 exists in the gas ...
Trang 862
The reason was the large size of the sample , in which the multiple reflection effect was pronounced and both the isotropic secondary extinc- tion , estimated according to Zachariasen , and absorp- tion ( ur = 2.5 ) were high .
The reason was the large size of the sample , in which the multiple reflection effect was pronounced and both the isotropic secondary extinc- tion , estimated according to Zachariasen , and absorp- tion ( ur = 2.5 ) were high .
Trang 1240
According to published data [ 2 , 3 , 6-9 ] , electronic spectra consisting of four bands are typical of porpyrin complexes of the diamine type . According to ' H NMR spectroscopy ( Table 1 ) , com- pound III , unlike chelate II ...
According to published data [ 2 , 3 , 6-9 ] , electronic spectra consisting of four bands are typical of porpyrin complexes of the diamine type . According to ' H NMR spectroscopy ( Table 1 ) , com- pound III , unlike chelate II ...
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Vol 48 No 5 | 622 |
Synthesis and Crystal Structure | 632 |
Synthesis and Study | 642 |
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absorption According acid activation addition analysis angles anion aqueous atoms band bond calculated cations changes characteristics Chem chemical Chemistry cluster cm-¹ complexes composition compounds concentration constants containing coordination Copyright corresponding crystal curves decrease dependence described determined distances distribution effect electron energy existence experimental extraction formation formed function groups H₂O heating higher hydrogen increases Inorganic intensity interaction involved ions Journal Khim lengths ligand lines measured metal method mixture mol/l molecules Moscow Neorg observed obtained oxide oxygen parameters phase Physics position prepared presence properties range ratio reaction REFERENCES refined reflections region respectively Russian salt samples Sciences shift shows signals similar solid solutions solubility solution solvent space group spectra spectrum stability structure studied synthesis Table temperature thermal tion unit values X-ray diffraction