Russian Journal of Inorganic Chemistry, Tập 41,Số phát hành 1-4British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1996 |
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Trang 59
... ligand and one of the equatorial CO groups , which seems to be responsible for a displacement of the nitrogen atom of the bridging ligand with respect to the midpoint of the Os ( 2 ) -Os ( 3 ) bond . Table 1. Coordinates of atoms in ( u ...
... ligand and one of the equatorial CO groups , which seems to be responsible for a displacement of the nitrogen atom of the bridging ligand with respect to the midpoint of the Os ( 2 ) -Os ( 3 ) bond . Table 1. Coordinates of atoms in ( u ...
Trang 131
... ligand complexes M ( C10H15N5P3O13 ) ( C4H8NO3 ) · 4H2O were synthesized from aqueous solutions of the ligands and metal hydroxides . According to IR spectroscopy ( 400-4000 cm - 1 ) , the ligands are coordinated to the metal ions : OH ...
... ligand complexes M ( C10H15N5P3O13 ) ( C4H8NO3 ) · 4H2O were synthesized from aqueous solutions of the ligands and metal hydroxides . According to IR spectroscopy ( 400-4000 cm - 1 ) , the ligands are coordinated to the metal ions : OH ...
Trang 135
... ligand complexes were obtained , and their forma- tion constants logß were determined to be 13.41 ( Cu ) , 12.52 ( Zn ) , 10.46 ( Ni ) , 9.53 ( Co ) , and 9.10 ( Mn ) . Mixed- ligand complexes of composition M ( C4H9NO3 ) ( C4H5N3O ) ...
... ligand complexes were obtained , and their forma- tion constants logß were determined to be 13.41 ( Cu ) , 12.52 ( Zn ) , 10.46 ( Ni ) , 9.53 ( Co ) , and 9.10 ( Mn ) . Mixed- ligand complexes of composition M ( C4H9NO3 ) ( C4H5N3O ) ...
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Vol 41 No 1 | 1 |
Synthesis and Characterization | 7 |
Deviation from Stoichiometry in Mercury Chalcochromite HgCr₂Se | 23 |
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absorption acetonitrile acetylacetonate acid Akad ammonium analysis angles anions aqueous solutions atoms band bismuth bond lengths calculated carbon cations chelate Chem chemical chloride cm-¹ cobalt(II complexes composition concentration COORDINATION COMPOUNDS coordination number coordination sphere copper(II corresponding crystal structure curves decomposition decrease determined electron energy English Translation Copyright equation equilibrium ethanol eutectic experimental extraction formation H₂O Hayka/Interperiodica Publishing Russia hydrazide hydrogen bonds increase Inorganic Chemistry interaction ionic ions Khim Khimiya lanthanide ligands melting metal method mixture mol/l molybdenum Moscow Nauk SSSR Nauka Neorg nitrate obtained Original Russian Text oxidation oxygen oxygen atoms parameters Pd(II peak phase Phys plexes potassium properties protons range ratio reaction redox Russia Received Russian Academy Russian Journal Russian Text Copyright salts samples sodium solvent spectra spectrum stretching vibrations studied sulfate synthesis Table temperature thermal tion unit cell values vanadium(V water molecules X-ray diffraction