Russian Journal of Inorganic Chemistry, Tập 41,Số phát hành 1-4British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1996 |
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Trang 242
... frequencies in transition element pentahalides are usually much higher than terminal halogen frequencies . The latter frequencies are similar to those of the corresponding hexahalides being , as expected , slightly lower [ 27 , 28 ] ...
... frequencies in transition element pentahalides are usually much higher than terminal halogen frequencies . The latter frequencies are similar to those of the corresponding hexahalides being , as expected , slightly lower [ 27 , 28 ] ...
Trang 243
... frequencies and how the changes of bridging and terminal halogen frequencies are related to each other . For this , we com- pared the 35CI NQR frequencies of axial and equatorial atoms with those of bridging atoms for the whole series ...
... frequencies and how the changes of bridging and terminal halogen frequencies are related to each other . For this , we com- pared the 35CI NQR frequencies of axial and equatorial atoms with those of bridging atoms for the whole series ...
Trang 244
... frequencies as compared to the terminal frequencies is caused by a pr - electron density increase due to a weaker pr¬dπ bonding between the bridging atoms and the metal . A difference between the bridging and terminal halo- gen frequencies ...
... frequencies as compared to the terminal frequencies is caused by a pr - electron density increase due to a weaker pr¬dπ bonding between the bridging atoms and the metal . A difference between the bridging and terminal halo- gen frequencies ...
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Vol 41 No 1 | 1 |
Synthesis and Characterization | 7 |
Deviation from Stoichiometry in Mercury Chalcochromite HgCr₂Se | 23 |
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absorption acetonitrile acetylacetonate acid Akad ammonium analysis angles anions aqueous solutions atoms band bismuth bond lengths calculated carbon cations chelate Chem chemical chloride cm-¹ cobalt(II complexes composition concentration COORDINATION COMPOUNDS coordination number coordination sphere copper(II corresponding crystal structure curves decomposition decrease determined electron energy English Translation Copyright equation equilibrium ethanol eutectic experimental extraction formation H₂O Hayka/Interperiodica Publishing Russia hydrazide hydrogen bonds increase Inorganic Chemistry interaction ionic ions Khim Khimiya lanthanide ligands melting metal method mixture mol/l molybdenum Moscow Nauk SSSR Nauka Neorg nitrate obtained Original Russian Text oxidation oxygen oxygen atoms parameters Pd(II peak phase Phys plexes potassium properties protons range ratio reaction redox Russia Received Russian Academy Russian Journal Russian Text Copyright salts samples sodium solvent spectra spectrum stretching vibrations studied sulfate synthesis Table temperature thermal tion unit cell values vanadium(V water molecules X-ray diffraction