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COORDINATION COMPOUNDS Effect of Chloro Substitution on the Coordination Properties of Metalloporphyrins N. Sh . Lebedeva , N. A. Pavlycheva , N. Zh . Mamardashvili , and A. I. V'yugin Institute of Solution Chemistry , Russian Academy ...
COORDINATION COMPOUNDS Effect of Chloro Substitution on the Coordination Properties of Metalloporphyrins N. Sh . Lebedeva , N. A. Pavlycheva , N. Zh . Mamardashvili , and A. I. V'yugin Institute of Solution Chemistry , Russian Academy ...
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Thus , the phenyl substituents in Zn ( 2 - Cl ) , TPP exhibit +1 and + C electronic effects with respect to the macrocycle ... This might be due to the mutual influence of chlorine atoms , which exhibit the -F substitution effect .
Thus , the phenyl substituents in Zn ( 2 - Cl ) , TPP exhibit +1 and + C electronic effects with respect to the macrocycle ... This might be due to the mutual influence of chlorine atoms , which exhibit the -F substitution effect .
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Meanwhile , the kinetic compensation effect is well defined in reaction ( 1 ) ( Fig . ... the difference in the reactivities must be related to the electronic effects of substituents , which are transmitted to the nitrogen atoms of the ...
Meanwhile , the kinetic compensation effect is well defined in reaction ( 1 ) ( Fig . ... the difference in the reactivities must be related to the electronic effects of substituents , which are transmitted to the nitrogen atoms of the ...
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Vol 48 No 9 | 1282 |
Simultaneous English language translation of the journal is available from MAIK NaukaInterperiodica Russia | 1446 |
Vol 48 No 11 2003 | 1615 |
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absorption acid activation analysis angles anion atoms band bond calculated cations Chem chemical Chemistry cm-¹ complexes components composition compounds concentration constant containing coordination Copyright corresponding crystal crystal structure curves decreases determined diagram distances effect electron energy experimental field formation formed function heating hydrogen increases Inorganic intensity interaction ions Journal Khim layer ligand materials measured melting metal method mixture molecules Moscow Neorg Note observed obtained oxidation oxygen parameters phase Physics positions prepared properties range ratio reaction REFERENCES refined reflections region respectively ring Russian salt samples Sciences shifts shown shows signals single sodium solid solid solutions solubility solutions space space group spectra spectrum spinel stability structure studied Synthesis Table temperature thermal tion trans transition Translation values vibrations X-ray diffraction