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Trang 1033
5 consider that the substitution by water of anionic ligands in complex cations of type [ Coxen takes place by a monomolecular nucleophilic substitution mechanism ( SN1 ) , but Brown et al . consider it to be a bimolecular mechanism ...
5 consider that the substitution by water of anionic ligands in complex cations of type [ Coxen takes place by a monomolecular nucleophilic substitution mechanism ( SN1 ) , but Brown et al . consider it to be a bimolecular mechanism ...
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KINETICS OF THE REACTION OF PLATI- NUM ( IV ) TETRAMMINES WITH AMMONIA AND PYRIDINE O.E. Zvyagintsev and E. F. Shu bochkina The kinetics and mechanism of substitution reactions in the coordination sphere of complex compounds is of in- ...
KINETICS OF THE REACTION OF PLATI- NUM ( IV ) TETRAMMINES WITH AMMONIA AND PYRIDINE O.E. Zvyagintsev and E. F. Shu bochkina The kinetics and mechanism of substitution reactions in the coordination sphere of complex compounds is of in- ...
Trang 1042
We suggest that these uncatalysed reactions involve direct substitution in the octahedral complexes in aqueous solution and take place by an SNo2 mechanism . This is con- firmed by the fact that the electrical conductivity of the ...
We suggest that these uncatalysed reactions involve direct substitution in the octahedral complexes in aqueous solution and take place by an SNo2 mechanism . This is con- firmed by the fact that the electrical conductivity of the ...
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Journal | 767 |
Brief Communications 1724 878 Solubility isotherm of the ureacadmium sulphatewater system at 30 | 878 |
THE PAGE NUMBERS 1599 819 Preparation and thermographic study of complexes of cadmium halides with | 1080 |
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absorption acid added addition Akad alcohol alkali alloys ammonia ammonium analysis anion aqueous atom bismuth bond calculated carbonate Chem chemical chloride complex components composition compounds concentration conductivity confirmed constant containing coordination corresponding crystallisation crystals curve decomposition decrease density dependence determined diagram dissolved effect equilibrium excess experiments formation formed given gives H₂O heating hydrogen hydroxide increase indices initial Inorg ions Khim lines liquid measured melting metal method mixture molar mole molecules Nauk SSSR Neorg nitrate observed obtained oxide peritectic phase platinum potassium precipitate prepared presence pressure pure quantity ratio reaction Received reduction refractive region Russ salt separated shown shows sodium solid solutions solubility solution solvent specimens stability structure studied substance sulphate Table temperature thermal tion values washed X-ray yield Zhur