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... of co- -ordinated Br " and Cl- ions depends on the nature of the neighbouring ligands ( the cis effect ) . ... change in the number j of one species of ligand is accompanied by a change in the charge of the co - ordination sphere .
... of co- -ordinated Br " and Cl- ions depends on the nature of the neighbouring ligands ( the cis effect ) . ... change in the number j of one species of ligand is accompanied by a change in the charge of the co - ordination sphere .
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8 shows the dependence of the logarithms of the formation constants of the complexes Cd ( NH ) -jI3 - 3 , and of the strength of the individual bonds , on the number of ligands . To calculate the strengths of the bonds , we used ...
8 shows the dependence of the logarithms of the formation constants of the complexes Cd ( NH ) -jI3 - 3 , and of the strength of the individual bonds , on the number of ligands . To calculate the strengths of the bonds , we used ...
Trang 1068
In calculating the ligand concentration [ A ] , the formation of a complex with three coordinated groups was allowed for . log K3 = Ex - Eo 0.059 2 + 3 log [ A ] . ( 2 ) The mean value of the instability constant exponent pK , is 10.81 ...
In calculating the ligand concentration [ A ] , the formation of a complex with three coordinated groups was allowed for . log K3 = Ex - Eo 0.059 2 + 3 log [ A ] . ( 2 ) The mean value of the instability constant exponent pK , is 10.81 ...
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Journal | 767 |
Brief Communications 1724 878 Solubility isotherm of the ureacadmium sulphatewater system at 30 | 878 |
THE PAGE NUMBERS 1599 819 Preparation and thermographic study of complexes of cadmium halides with | 1080 |
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absorption acid added addition Akad alcohol alkali alloys ammonia ammonium analysis anion aqueous atom bismuth bond calculated carbonate Chem chemical chloride complex components composition compounds concentration conductivity confirmed constant containing coordination corresponding crystallisation crystals curve decomposition decrease density dependence determined diagram dissolved effect equilibrium excess experiments formation formed given gives H₂O heating hydrogen hydroxide increase indices initial Inorg ions Khim lines liquid measured melting metal method mixture molar mole molecules Nauk SSSR Neorg nitrate observed obtained oxide peritectic phase platinum potassium precipitate prepared presence pressure pure quantity ratio reaction Received reduction refractive region Russ salt separated shown shows sodium solid solutions solubility solution solvent specimens stability structure studied substance sulphate Table temperature thermal tion values washed X-ray yield Zhur