Russian Journal of Inorganic Chemistry, Tập 6,Số phát hành 7-12British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1961 |
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... ligand with the highest reduction potential . With increase in the difference between these potentials , the ligands X and Y compete with one another for the valency orbitals of the central ion , the ligand with the higher reduction ...
... ligand with the highest reduction potential . With increase in the difference between these potentials , the ligands X and Y compete with one another for the valency orbitals of the central ion , the ligand with the higher reduction ...
Trang 1068
... ligand concentration [ A ] , the formation of a complex with three coordinated groups was allowed for . log K , = Ex - Eo Ео 0.059 + 3 log [ A ] . ( 2 ) The mean value of the instability constant exponent pK , is 10.81 ± 0.05 . 2. The ...
... ligand concentration [ A ] , the formation of a complex with three coordinated groups was allowed for . log K , = Ex - Eo Ео 0.059 + 3 log [ A ] . ( 2 ) The mean value of the instability constant exponent pK , is 10.81 ± 0.05 . 2. The ...
Trang 1264
... ligand ( Ca ) is found from the equationt ca - complex = ca. where ca is the initial ligand concentration . ( 4a ) An arbitrary equilibrium constant for the reaction can be calculated from the equation † Since in this range of oxalic ...
... ligand ( Ca ) is found from the equationt ca - complex = ca. where ca is the initial ligand concentration . ( 4a ) An arbitrary equilibrium constant for the reaction can be calculated from the equation † Since in this range of oxalic ...
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acid Akad alcohol alkali alloys aluminium ammonia ammonium anion aqueous solution Blagorod bromide cadmium caesium calculated carbonate cerium Chem chemical chloride coefficient complex ion composition concentration copper corresponding cristobalite crystallisation crystals decomposition determined dissociation electrode equilibrium diagram ether ethyl eutectic formation formed gallium glauberite H₂O H₂SO heating curve hydrogen hydroxide increase indium Inorg Inst instability constant ionic strength isotherms K₂SO Khim ligands liquid lithium melting metal method molar ratio molar volumes mole molecules MTPC Na₂SO NaCl Nauk SSSR neodymium Neorg nitrate nitrilotriacetic acid NO₂ Obshch obtained oxide platinum Platiny Drug polyhalite potassium praseodymium precipitate prepared pyridine reaction reagent refractive refractive indices Russ salt saturated shows sodium solid phase solid solutions solubility solvents stability studied sulphate sulphide Table temperature thallium tin selenide tion titanium trans effect uranyl values X-ray Zhur zinc zirconium