Russian Journal of Inorganic Chemistry, Tập 6,Số phát hành 7-12British Library Lending Division with the cooperation of the Royal Society of Chemistry, 1961 |
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Trang 1033
... kinetics of substitution reactions en- ables their mechanism to be established in some cases , so enabling rational methods to be selected for the preparation of cobalt aquoammines and acidoaquoammines . Moreover , comparison of the kinetic ...
... kinetics of substitution reactions en- ables their mechanism to be established in some cases , so enabling rational methods to be selected for the preparation of cobalt aquoammines and acidoaquoammines . Moreover , comparison of the kinetic ...
Trang 1040
... kinetic charac- teristics of these reactions are given in Tables 1 and 2 . In addition to the study of the kinetics of the replacement of halogen by amine in the PtIV tetrammines by potentio- metric titration of the unreacted amine , we ...
... kinetic charac- teristics of these reactions are given in Tables 1 and 2 . In addition to the study of the kinetics of the replacement of halogen by amine in the PtIV tetrammines by potentio- metric titration of the unreacted amine , we ...
Trang 1041
... Kinetic characteristics for the reactions of tetrammines with pyridine . Reaction NH NH , ་ ་ ལ་ Pt NH3 Br 25 ° 30 ° 35 ° E log z 10 K , 10 K2 10 K , ( NO3 ) 2 + Py 3.0 5.1 8.6 19 200 10.49 NH3 NH2 Pt ( NO3 ) 2 + Py 6.6 10.7 17.1 17 300 ...
... Kinetic characteristics for the reactions of tetrammines with pyridine . Reaction NH NH , ་ ་ ལ་ Pt NH3 Br 25 ° 30 ° 35 ° E log z 10 K , 10 K2 10 K , ( NO3 ) 2 + Py 3.0 5.1 8.6 19 200 10.49 NH3 NH2 Pt ( NO3 ) 2 + Py 6.6 10.7 17.1 17 300 ...
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acid Akad alcohol alkali alloys aluminium ammonia ammonium anion aqueous solution Blagorod bromide cadmium caesium calculated carbonate cerium Chem chemical chloride coefficient complex ion composition concentration copper corresponding cristobalite crystallisation crystals decomposition determined dissociation electrode equilibrium diagram ether ethyl eutectic formation formed gallium glauberite H₂O H₂SO heating curve hydrogen hydroxide increase indium Inorg Inst instability constant ionic strength isotherms K₂SO Khim ligands liquid lithium melting metal method molar ratio molar volumes mole molecules MTPC Na₂SO NaCl Nauk SSSR neodymium Neorg nitrate nitrilotriacetic acid NO₂ Obshch obtained oxide platinum Platiny Drug polyhalite potassium praseodymium precipitate prepared pyridine reaction reagent refractive refractive indices Russ salt saturated shows sodium solid phase solid solutions solubility solvents stability studied sulphate sulphide Table temperature thallium tin selenide tion titanium trans effect uranyl values X-ray Zhur zinc zirconium