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Enthalpies ( kJ / mol ) of reactions ( 10 ) tion of the crystal hydrates ( Table 3 ) ; the literature values of the standard enthalpies of formation of Initial crystal hydrate A , Ho ( 298 ) 4 , h10 ( 298 ) * Zr ( HPO4 ) 2 · H2O ( -3 ...
Enthalpies ( kJ / mol ) of reactions ( 10 ) tion of the crystal hydrates ( Table 3 ) ; the literature values of the standard enthalpies of formation of Initial crystal hydrate A , Ho ( 298 ) 4 , h10 ( 298 ) * Zr ( HPO4 ) 2 · H2O ( -3 ...
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Scheme of calculating the standard enthalpies of M " ( NaAsO4 ) 2 formation at 298.15 K : 4 , H16 ( 298 ) = 4,4 ° ( 298 ) = A , H ? ( 298 ) + A , H ; ( 298 ) + A , H. ( 298 ) – A , H. ( 298 ) - A , H1 ( 298 ) + A , H42 ( 298 ) + A ...
Scheme of calculating the standard enthalpies of M " ( NaAsO4 ) 2 formation at 298.15 K : 4 , H16 ( 298 ) = 4,4 ° ( 298 ) = A , H ? ( 298 ) + A , H ; ( 298 ) + A , H. ( 298 ) – A , H. ( 298 ) - A , H1 ( 298 ) + A , H42 ( 298 ) + A ...
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Enthalpies ( kJ / mol ) of reactions ( 17 ) at 298.15 K 9 = Initial crystal hydrate 4 , H7 ( 298 ) 4 , H7 ( 298 ) * whose enthalpy , according to Hess's law , is 4 , H ° ( 298 ) = 4 , H ° ( 298 , Zr ( NaPO4 ) 2 , cr ) – – AH ° ( 298 ...
Enthalpies ( kJ / mol ) of reactions ( 17 ) at 298.15 K 9 = Initial crystal hydrate 4 , H7 ( 298 ) 4 , H7 ( 298 ) * whose enthalpy , according to Hess's law , is 4 , H ° ( 298 ) = 4 , H ° ( 298 , Zr ( NaPO4 ) 2 , cr ) – – AH ° ( 298 ...
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absorption according acid added addition analysis angle anions aqueous atoms band bond bridging calculated cation changes charge Chem chemical Chemistry chloride complexes composition compounds concentration constant containing coordination Copyright corresponding crystal curves decomposition decrease derivatives described determined diagram distances effect electron energy enthalpies experimental extraction formation frequencies heating higher hydrogen increase indicates initial Inorganic intensity interaction ions Khim kJ/mol ligand measured melt metal method mixed mixtures mol/l molecules Moscow Neorg observed obtained occur oxide oxygen parameters phase phosphate positions powder prepared presented properties Publishing range ratio reaction REFERENCES region respectively Russian salts samples shift shows similar sodium solid solution space group spectra spectrum stability structure studied synthesis Table temperature thermal tion Translation unit values vibrations X-ray diffraction